Electronic and energy level engineering of directly fused porphyrin-conjugated polymers - impact of the central metal cation.
Journal
Journal of materials chemistry. C
ISSN: 2050-7526
Titre abrégé: J Mater Chem C Mater
Pays: England
ID NLM: 101601114
Informations de publication
Date de publication:
10 Feb 2022
10 Feb 2022
Historique:
received:
11
11
2021
accepted:
23
12
2021
entrez:
21
3
2022
pubmed:
22
3
2022
medline:
22
3
2022
Statut:
epublish
Résumé
The integration of porphyrins and their derivatives in functional devices for solar-assisted fuel production is both highly attractive and challenging due to the difficulties in processing them. This limitation is overcome in the gas-phase approach, particularly by oxidative chemical vapor deposition (oCVD), leading to the simultaneous synthesis and deposition of conjugated porphyrin coatings. We have investigated the impact of the metal cation of 5,15-diphenyl metalloporphyrins (MDPP; M = Co, Cu, Mg, Zn, Pd, Pt, Ag, Ru, Ag, and FeCl) on the dehydrogenative coupling reaction leading to fused-metalloporphyrin thin films
Identifiants
pubmed: 35308894
doi: 10.1039/d1tc05452j
pii: d1tc05452j
pmc: PMC8830115
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2194-2204Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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