Synthesis, aromatization and cavitates of an oxanorbornene-fused dibenzo[
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
23 Feb 2022
23 Feb 2022
Historique:
received:
24
11
2021
accepted:
12
01
2022
entrez:
21
3
2022
pubmed:
22
3
2022
medline:
22
3
2022
Statut:
epublish
Résumé
Oxanorbornene-fused double-stranded macrocycles, represented by kohnkene, are not only synthetic precursors toward short segments of zigzag carbon nanotubes but also typical cavitands processing an intrinsic cavity. However, their capability to bind guest molecules in solution remained unexplored. Herein we report a new member of oxanorbornene-fused double-stranded macrocycles, which is named a nanobox herein because of its shape. Reductive aromatization of this oxanorbornene-fused nanobox leads to observation of a new zigzag carbon nanobelt by high resolution mass spectroscopy. The fluorescence titration and NMR experiments indicate that this nanobox encapsulates C
Identifiants
pubmed: 35310504
doi: 10.1039/d1sc06553j
pii: d1sc06553j
pmc: PMC8864699
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2280-2285Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts of interest to declare.
Références
J Am Chem Soc. 2020 Mar 11;142(10):4576-4580
pubmed: 32084314
Chemistry. 2013 Oct 11;19(42):14061-8
pubmed: 24108598
Chemphyschem. 2010 Mar 15;11(4):799-803
pubmed: 20157914
Chemistry. 2020 Nov 20;26(65):14791-14801
pubmed: 32572996
Angew Chem Int Ed Engl. 2021 Apr 26;60(18):10311-10318
pubmed: 33599364
Chemistry. 2015 Apr 7;21(15):5742-9
pubmed: 25753916
Angew Chem Int Ed Engl. 2019 Jul 1;58(27):9038-9042
pubmed: 31026104
Chem Commun (Camb). 2019 Feb 19;55(16):2332-2335
pubmed: 30724314
Acta Crystallogr B. 2004 Dec;60(Pt 6):627-68
pubmed: 15534375
Chem Rev. 2013 Aug 14;113(8):5989-6113
pubmed: 23635015
Angew Chem Int Ed Engl. 2020 Aug 24;59(35):15124-15128
pubmed: 32428338
Org Lett. 2016 Jul 1;18(13):3054-7
pubmed: 27281035
Angew Chem Int Ed Engl. 2011 Aug 29;50(36):8342-4
pubmed: 21770005
J Am Chem Soc. 2021 Jun 16;143(23):8619-8624
pubmed: 34086453
Chem Soc Rev. 2007 Feb;36(2):189-97
pubmed: 17264922
Angew Chem Int Ed Engl. 2007;46(1-2):202-5
pubmed: 17031895
J Am Chem Soc. 2019 Nov 20;141(46):18500-18507
pubmed: 31710474
Acc Chem Res. 2009 Aug 18;42(8):1108-16
pubmed: 19469494
Chemistry. 2003 Jun 16;9(12):2745-57
pubmed: 12866537
Nat Chem. 2021 Mar;13(3):255-259
pubmed: 33495606
Nat Chem. 2021 May;13(5):402-419
pubmed: 33859393
Chem Sci. 2015 Feb 1;6(2):909-916
pubmed: 29560176
Angew Chem Int Ed Engl. 2020 May 11;59(20):7700-7705
pubmed: 32149448
Angew Chem Int Ed Engl. 2019 May 6;58(19):6244-6249
pubmed: 30843633
Org Lett. 2019 Dec 20;21(24):10120-10124
pubmed: 31814409
Science. 2017 Apr 14;356(6334):172-175
pubmed: 28408599
Angew Chem Int Ed Engl. 2021 Feb 1;60(5):2658-2662
pubmed: 33047813
Nat Chem. 2015 Aug;7(8):623-8
pubmed: 26201737