Temperature dependence of aging dynamics in highly non-equilibrium model polymer glasses.

A central feature of the non-equilibrium glassy "state" is its tendency to age toward equilibrium, obeying signatures identified by Kovacs over 50 years ago. The origin of these signatures, their fate far from equilibrium and at high temperatures, and the underlying nature of the glassy "state" far from equilibrium remain unsettled. Here, we simulate physical aging of polymeric glasses, driven much farther from equilibrium and at much higher temperatures than possible in experimental melt-quenched glasses. While these glasses exhibit Kovacs' signatures of glassy aging at sufficiently low temperatures, these signatures disappear above the onset T