How to obtain reaction free energies from free-energy profiles.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
21 Mar 2022
Historique:
entrez: 23 3 2022
pubmed: 24 3 2022
medline: 24 3 2022
Statut: ppublish

Résumé

For chemical reactions that occur via the rearrangement of atoms from a configuration about one minimum (reactant, R) of the potential energy surface (PES) to a configuration about another minimum (product, P), an exact relation between the Helmholtz reaction free energy (ΔF

Identifiants

pubmed: 35317588
doi: 10.1063/5.0083423
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

114105

Auteurs

Johannes C B Dietschreit (JCB)

Chair of Theoretical Chemistry, Department of Chemistry, University of Munich (LMU), Butenandtstr. 7, D-81377 München, Germany.

Dennis J Diestler (DJ)

University of Nebraska-Lincoln, Lincoln, Nebraska 68583, USA.

Christian Ochsenfeld (C)

Chair of Theoretical Chemistry, Department of Chemistry, University of Munich (LMU), Butenandtstr. 7, D-81377 München, Germany.

Classifications MeSH