Tailoring the Intersystem Crossing and Triplet Dynamics of Free-Base Octaalkyl-β-oxo-Substituted Porphyrins: Competing Effects of Spin-Vibronic and NH Tautomerism Relaxation Channels.


Journal

The journal of physical chemistry. A
ISSN: 1520-5215
Titre abrégé: J Phys Chem A
Pays: United States
ID NLM: 9890903

Informations de publication

Date de publication:
28 Apr 2022
Historique:
pubmed: 30 3 2022
medline: 30 3 2022
entrez: 29 3 2022
Statut: ppublish

Résumé

We demonstrate that β-oxo-substitution provides effective fine-tuning of both steady-state and transient electronic properties of octaalkyl-β-mono-oxochlorin and all isomers of the β,β'-dioxo-substituted chromophores. The addition of a carbonyl group increases the Q

Identifiants

pubmed: 35348324
doi: 10.1021/acs.jpca.2c01225
pmc: PMC9059185
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2522-2531

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Auteurs

Sayantan Bhattacharya (S)

Department of Chemistry, The University of Sheffield, Sheffield S3 7HF, United Kingdom.

Arthur Graf (A)

Department of Chemistry, The University of Sheffield, Sheffield S3 7HF, United Kingdom.

Anna Karolyna M S Gomes (AKMS)

Instituto de Química (IQ), Federal University of Rio de Janeiro, Rio de Janeiro 21941-909, Brazil.

Nivedita Chaudhri (N)

Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States.

Dimitri Chekulaev (D)

Department of Chemistry, The University of Sheffield, Sheffield S3 7HF, United Kingdom.

Christian Brückner (C)

Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States.

Thiago M Cardozo (TM)

Instituto de Química (IQ), Federal University of Rio de Janeiro, Rio de Janeiro 21941-909, Brazil.

Adrien A P Chauvet (AAP)

Department of Chemistry, The University of Sheffield, Sheffield S3 7HF, United Kingdom.

Classifications MeSH