The Complex Roles of Adenosine Triphosphate in Bioenergetics.


Journal

Chembiochem : a European journal of chemical biology
ISSN: 1439-7633
Titre abrégé: Chembiochem
Pays: Germany
ID NLM: 100937360

Informations de publication

Date de publication:
18 05 2022
Historique:
revised: 16 03 2022
received: 29 01 2022
pubmed: 31 3 2022
medline: 21 5 2022
entrez: 30 3 2022
Statut: ppublish

Résumé

ATP is generally defined as the "energy currency" of the cell. Its phosphoanhydride P-O bonds are often considered to be "high energy" linkages that release free energy when broken, and its hydrolysis is described as "strongly exergonic". However, breaking bonds cannot release energy and ATP hydrolysis in motor and active transport proteins is not "strongly exergonic". So, the relevance of ATP resides elsewhere. As important as the nucleotide are the proteins that undergo functionally relevant conformational changes upon both ATP binding and release of ADP and inorganic phosphate. ATP phosphorylates proteins for signaling, active transport, and substrates in condensation reactions. The ensuing dephosphorylation has different consequences in each case. In signaling and active transport the phosphate group is hydrolyzed whereas in condensation reactions the phosphoryl fragment acts as a dehydrating agent. As it will be discussed in this article, ATP does much more than simply contribute free energy to biological processes.

Identifiants

pubmed: 35353443
doi: 10.1002/cbic.202200064
doi:

Substances chimiques

Phosphates 0
Adenosine Diphosphate 61D2G4IYVH
Adenosine Triphosphate 8L70Q75FXE

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202200064

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Juan C Fontecilla-Camps (JC)

Univ. Grenoble Alpes, CEA, CNRS, IBS, Metalloproteins Unit, 38044, Grenoble, France.

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