Comb-type polymer-hybridized MXene nanosheets dispersible in arbitrary polar, nonpolar, and ionic solvents.


Journal

Science advances
ISSN: 2375-2548
Titre abrégé: Sci Adv
Pays: United States
ID NLM: 101653440

Informations de publication

Date de publication:
Apr 2022
Historique:
entrez: 30 3 2022
pubmed: 31 3 2022
medline: 31 3 2022
Statut: ppublish

Résumé

Solution-based processing of two-dimensional (2D) nanomaterials is highly desirable, especially for the low-temperature large-area fabrication of flexible multifunctional devices. MXenes, an emerging family of 2D materials composed of transition metal carbides, carbonitrides, or nitrides, provide excellent electrical and electrochemical properties through aqueous processing. Here, we further expand the horizon of MXene processing by introducing a polymeric superdispersant for MXene nanosheets. Segmented anchor-spacer structures of a comb-type polymer, polycarboxylate ether (PCE), provide polymer grafting-like steric spacings over the van der Waals range of MXene surfaces, thereby reducing the colloidal interactions by the order of 10

Identifiants

pubmed: 35353563
doi: 10.1126/sciadv.abl5299
pmc: PMC8967220
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

eabl5299

Références

ACS Nano. 2019 Oct 22;13(10):11392-11400
pubmed: 31553884
ACS Appl Mater Interfaces. 2013 Apr 10;5(7):2302-15
pubmed: 23446358
Science. 2016 Sep 9;353(6304):1137-40
pubmed: 27609888
ACS Appl Mater Interfaces. 2019 Mar 13;11(10):10198-10207
pubmed: 30689343
Adv Mater. 2017 Jan;29(1):
pubmed: 27797119
Proc Natl Acad Sci U S A. 2014 Nov 25;111(47):16676-81
pubmed: 25389310
ACS Nano. 2019 Dec 24;13(12):13818-13828
pubmed: 31738507
Nano Lett. 2017 Jan 11;17(1):384-391
pubmed: 28026960
ACS Omega. 2018 Mar 05;3(3):2609-2617
pubmed: 31458547
ACS Nano. 2018 Feb 27;12(2):986-993
pubmed: 29368519
Adv Mater. 2016 Feb 17;28(7):1517-22
pubmed: 26660424
Small. 2018 Nov;14(45):e1802479
pubmed: 30295015
Langmuir. 2016 May 24;32(20):5058-68
pubmed: 27143102
Nat Commun. 2020 Mar 10;11(1):1302
pubmed: 32157089
Adv Sci (Weinh). 2018 Jul 04;5(9):1800502
pubmed: 30250792
Adv Mater. 2017 Oct;29(37):
pubmed: 28741708
Chem Commun (Camb). 2016 Dec 22;53(2):400-403
pubmed: 27958604
ACS Nano. 2017 Mar 28;11(3):2459-2469
pubmed: 27998055
J Colloid Interface Sci. 2020 Mar 7;562:204-212
pubmed: 31838356
ACS Nano. 2018 Dec 26;12(12):12464-12471
pubmed: 30495925
Nature. 2014 Dec 4;516(7529):78-81
pubmed: 25470044
Phys Rev Lett. 2007 Oct 26;99(17):178301
pubmed: 17995376
Sci Adv. 2018 Jun 15;4(6):eaat0098
pubmed: 29922718
ACS Nano. 2012 Jan 24;6(1):63-73
pubmed: 22017285

Auteurs

Gyeong Seok Park (GS)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Dong Hae Ho (DH)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Benzheng Lyu (B)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Seungbae Jeon (S)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Du Yeol Ryu (DY)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Dae Woo Kim (DW)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Namkon Lee (N)

Department of Structure Research, Korea Institute of Civil Engineering and Building Technology (KICT), Goyang, Gyonggi-Do 10223, Korea.

Sungwook Kim (S)

Department of Structure Research, Korea Institute of Civil Engineering and Building Technology (KICT), Goyang, Gyonggi-Do 10223, Korea.

Young Jae Song (YJ)

SKKU Advanced Institute of Nanotechnology (SAINT), Departments of Nano Engineering and Physics, Sungkyunkwan University, Suwon, Gyeonggi-Do 440-746, Korea.

Sae Byeok Jo (SB)

School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea.

Jeong Ho Cho (JH)

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea.

Classifications MeSH