Brain-targeting, acid-responsive antioxidant nanoparticles for stroke treatment and drug delivery.

A-BAM NPs, A-BAM NPs ALT, alanine aminotransferase AST, aspartate aminotransferase Acid-triggered release Antioxidant nanoparticles BA, betulinic acid BAM, betulinic amine BBB, blood brain barrier BIRDS, biosensor imaging of redundant deviation in shifts BT, ß-sitosterol DLS, dynamic light scattering DTA, dehydrotrametenolic acid DYDA, diketohydrindylidene diketohydrindamine Drug delivery GA, glycyrrhetic acid Ischemic stroke LCMS, liquid chromatography mass spectrometry LP, lupeol MCAO, middle cerebral artery occlusion NA1 NMR, nuclear magnetic resonance NP, nanoparticle OA, oleanolic acid PAA, poricoic acid PEG, polyethylene glycol SA, sumaresinolic acid SEM, scanning electron microscopy ST, stigmasterol TEM, transmission electron microscope TTC, triphenyltetrazolium chloride UA, ursolic acid tPA, tissue-type plasminogen activator

Journal

Bioactive materials
ISSN: 2452-199X
Titre abrégé: Bioact Mater
Pays: China
ID NLM: 101685294

Informations de publication

Date de publication:
Oct 2022
Historique:
received: 22 11 2021
revised: 02 02 2022
accepted: 28 02 2022
entrez: 7 4 2022
pubmed: 8 4 2022
medline: 8 4 2022
Statut: epublish

Résumé

Stroke is the leading cause of death and disability. Currently, there is no effective pharmacological treatment for this disease, which can be partially attributed to the inability to efficiently deliver therapeutics to the brain. Here we report the development of natural compound-derived nanoparticles (NPs), which function both as a potent therapeutic agent for stroke treatment and as an efficient carrier for drug delivery to the ischemic brain. First, we screened a collection of natural nanomaterials and identified betulinic acid (BA) as one of the most potent antioxidants for stroke treatment. Next, we engineered BA NPs for preferential drug release in acidic ischemic tissue through chemically converting BA to betulinic amine (BAM) and for targeted drug delivery through surface conjugation of AMD3100, a CXCR4 antagonist. The resulting AMD3100-conjugated BAM NPs, or A-BAM NPs, were then assessed as a therapeutic agent for stroke treatment and as a carrier for delivery of NA1, a neuroprotective peptide. We show that intravenous administration of A-BAM NPs effectively improved recovery from stroke and its efficacy was further enhanced when NA1 was encapsulated. Due to their multifunctionality and significant efficacy, we anticipate that A-BAM NPs have the potential to be translated both as a therapeutic agent and as a drug carrier to improve the treatment of stroke.

Identifiants

pubmed: 35386312
doi: 10.1016/j.bioactmat.2022.02.033
pii: S2452-199X(22)00109-8
pmc: PMC8958421
doi:

Types de publication

Journal Article

Langues

eng

Pagination

57-65

Subventions

Organisme : NINDS NIH HHS
ID : R01 NS110721
Pays : United States
Organisme : NCATS NIH HHS
ID : UL1 TR001863
Pays : United States

Informations de copyright

© 2022 The Authors.

Déclaration de conflit d'intérêts

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Auteurs

Shenqi Zhang (S)

Department of Neurosurgery, USA.
Department of Neurosurgery, Renmin Hospital of Wuhan University, Wuhan, Hubei, 430060, China.

Bin Peng (B)

Department of Neurosurgery, USA.

Zeming Chen (Z)

Department of Neurosurgery, USA.

Jiang Yu (J)

Department of Neurosurgery, USA.

Gang Deng (G)

Department of Neurosurgery, USA.

Youmei Bao (Y)

Department of Neurosurgery, USA.

Chao Ma (C)

Department of Neurosurgery, USA.

Fengyi Du (F)

Department of Neurosurgery, USA.

Wendy C Sheu (WC)

Department of Biomedical Engineering, USA.

W Taylor Kimberly (WT)

Department of Neurology, Division of Neurocritical Care, Massachusetts General Hospital, Boston, MA, USA.

J Marc Simard (JM)

Department of Neurosurgery, University of Maryland School of Medicine, Baltimore, MD, 21201, USA.

Daniel Coman (D)

Department of Radiology and Biomedical Imaging, USA.

Qianxue Chen (Q)

Department of Neurosurgery, Renmin Hospital of Wuhan University, Wuhan, Hubei, 430060, China.

Fahmeed Hyder (F)

Department of Biomedical Engineering, USA.
Department of Radiology and Biomedical Imaging, USA.

Jiangbing Zhou (J)

Department of Neurosurgery, USA.
Department of Biomedical Engineering, USA.

Kevin N Sheth (KN)

Department of Neurosurgery, USA.
Department of Neurology, Yale University, New Haven, CT, 06510, USA.

Classifications MeSH