In Situ Hydrolysis of Block Copolymers at the Water-Oil Interface.
Block Copolymers
In Situ Hydrolysis
Interfaces
Reconfiguration
Self-Assembly
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
20 Jun 2022
20 Jun 2022
Historique:
received:
25
01
2022
pubmed:
8
4
2022
medline:
8
4
2022
entrez:
7
4
2022
Statut:
ppublish
Résumé
In situ manipulation of the chemical composition of block copolymers at the fluid interfaces affords a route by which the interfacial tension, the packing of the copolymers, and the penetration of the blocks into the two liquids can be controlled. Here, a series of linear block copolymers of poly(solketal methacrylate-b-styrene) (PSM-b-PS) are used, converting hydrophobic PSM block into a hydrophilic glycerol monomethacrylate (GM) block, that results in a marked decrease in the liquid-liquid interfacial tension. The kinetics of the first-order hydrolysis reaction was analyzed by monitoring the time-dependent interfacial tension as a function of pH, polymer concentration, molecular weight, and composition. Fluorescence recovery after photobleaching (FRAP) was used to measure the in-plane dynamics of the copolymers before and after hydrolysis. This work provides insights into a quantitative pathway by which in situ interfacial reactions may be performed and monitored in real time, completely changing the interfacial activity of the molecule.
Identifiants
pubmed: 35388568
doi: 10.1002/anie.202201392
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201392Subventions
Organisme : Air Force Office of Scientific Research
ID : FA9550-21-1-0388
Organisme : Army Research Laboratory
ID : W911NF-20-0093
Informations de copyright
© 2022 Wiley-VCH GmbH.
Références
M. Hu, T. P. Russell, Mater. Chem. Front. 2021, 5, 1205-1220;
P. S. Clegg, J. W. Tavacoli, P. J. Wilde, Soft Matter 2016, 12, 998-1008.
G. Xie, P. Krys, R. D. Tilton, K. Matyjaszewski, Macromolecules 2017, 50, 2942-2950;
J. A. Hanson, C. B. Chang, S. M. Graves, Z. Li, T. G. Mason, T. J. Deming, Nature 2008, 455, 85-88;
W. Li, Y. Yu, M. Lamson, M. S. Silverstein, R. D. Tilton, K. Matyjaszewski, Macromolecules 2012, 45, 9419-9426.
H. C. Shum, Y. J. Zhao, S. H. Kim, D. A. Weitz, Angew. Chem. Int. Ed. 2011, 50, 1648-1651;
Angew. Chem. 2011, 123, 1686-1689.
Y. Jiang, R. Chakroun, P. Gu, A. H. Groschel, T. P. Russell, Angew. Chem. Int. Ed. 2020, 59, 12751-12755;
Angew. Chem. 2020, 132, 12851-12855.
J. Zhao, Z. Pan, D. Snyder, H. A. Stone, T. Emrick, J. Am. Chem. Soc. 2021, 143, 5558-5564;
K. H. Ku, J. M. Shin, D. Klinger, S. G. Jang, R. C. Hayward, C. J. Hawker, B. J. Kim, ACS Nano 2016, 10, 5243-5251.
J. Bae, T. P. Russell, R. C. Hayward, Angew. Chem. Int. Ed. 2014, 53, 8240-8245;
Angew. Chem. 2014, 126, 8379-8384;
Y. Chai, A. Lukito, Y. Jiang, P. D. Ashby, T. P. Russell, Nano Lett. 2017, 17, 6453-6457;
Q. Chen, Y. Xu, X. Cao, L. Qin, Z. An, Polym. Chem. 2014, 5, 175-185;
D. J. French, J. Fowler, P. Taylor, P. S. Clegg, Soft Matter 2020, 16, 7342-7349.
A. Salonen, D. Langevin, P. Perrin, Soft Matter 2010, 6, 5308-5311;
J. Lee, K. H. Ku, J. Kim, Y. J. Lee, S. G. Jang, B. J. Kim, J. Am. Chem. Soc. 2019, 141, 15348-15355.
R. H. Staff, M. Gallei, M. Mazurowski, M. Rehahn, R. Berger, K. Landfester, D. Crespy, ACS Nano 2012, 6, 9042-9049.
M. J. T. Raaijmakers, N. E. Benes, Prog. Polym. Sci. 2016, 63, 86-142;
K. Piradashvili, E. M. Alexandrino, F. R. Wurm, K. Landfester, Chem. Rev. 2016, 116, 2141-2169;
Z. Niu, J. He, T. P. Russell, Q. Wang, Angew. Chem. Int. Ed. 2010, 49, 10052-10066;
Angew. Chem. 2010, 122, 10250-10265.
D. M. Yu, D. M. Smith, H. Kim, J. Rzayev, T. P. Russell, Macromolecules 2019, 52, 6458-6466;
D. M. Yu, D. M. Smith, H. Kim, J. K. D. Mapas, J. Rzayev, T. P. Russell, Macromolecules 2019, 52, 3592-3600;
D. M. Yu, J. K. D. Mapas, H. Kim, J. Choi, A. E. Ribbe, J. Rzayev, T. P. Russell, Macromolecules 2018, 51, 1031-1040;
G. Jeong, D. M. Yu, J. K. D. Mapas, Z. Sun, J. Rzayev, T. P. Russell, Macromolecules 2017, 50, 7148-7154;
M. Hu, X. Li, J. Rzayev, T. P. Russell, Macromolecules 2021, 54, 11449-11458.
Y. Lin, A. Boker, H. Skaff, D. Cookson, A. D. Dinsmore, T. Emrick, T. P. Russell, Langmuir 2005, 21, 191-194;
B. Frank, A. P. Gast, T. P. Russell, H. R. Brown, C. Hawker, Macromolecules 1996, 29, 6531-6534;
D. Axelrod, D. E. Koppel, J. Schlessinger, E. Elson, W. W. Webb, Biophys. J. 1976, 16, 1055-1069.
D. M. Barber, Z. Yang, L. Prévost, O. du Roure, A. Lindner, T. Emrick, A. J. Crosby, Adv. Funct. Mater. 2020, 30, 2002704.
K. Du, E. Glogowski, T. Emrick, T. P. Russell, A. D. Dinsmore, Langmuir 2010, 26, 12518-12522.
L. P. Ozorio, R. Pianzolli, M. B. S. Mota, C. J. A. Mota, J. Braz. Chem. Soc. 2012, 23, 931-937.
T. P. Russell, G. Coulon, V. R. Deline, D. C. Miller, Macromolecules 1989, 22, 4600-4606;
G. Coulon, T. P. Russell, V. R. Deline, P. F. Green, Macromolecules 1989, 22, 2581-2589.
M. M. Martin, L. Lindqvist, J. Lumin. 1975, 10, 381-390.