Engineering Periodic Dinuclear Lanthanide-Directed Networks Featuring Tunable Energy Level Alignment and Magnetic Anisotropy by Metal Exchange.
X-ray magnetic circular dichroism
lanthanides
magnetic anisotropy
metal exchange
metal-organic networks
scanning tunneling microscopy
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Jun 2022
Jun 2022
Historique:
revised:
16
02
2022
received:
16
11
2021
pubmed:
9
4
2022
medline:
9
4
2022
entrez:
8
4
2022
Statut:
ppublish
Résumé
The design of lanthanide multinuclear networks is an emerging field of research due to the potential of such materials for nanomagnetism, spintronics, and quantum information. Therefore, controlling their electronic and magnetic properties is of paramount importance to tailor the envisioned functionalities. In this work, a multidisciplinary study is presented combining scanning tunneling microscopy, scanning tunneling spectroscopy, X-ray absorption spectroscopy, X-ray linear dichroism, X-ray magnetic circular dichroism, density functional theory, and multiplet calculations, about the supramolecular assembly, electronic and magnetic properties of periodic dinuclear 2D networks based on lanthanide-pyridyl interactions on Au(111). Er- and Dy-directed assemblies feature identical structural architectures stabilized by metal-organic coordination. Notably, despite exhibiting the same +3 oxidation state, there is a shift of the energy level alignment of the unoccupied molecular orbitals between Er- and Dy-directed networks. In addition, there is a reorientation of the easy axis of magnetization and an increment of the magnetic anisotropy when the metallic center is changed from Er to Dy. Thus, the results show that it is feasible to tune the energy level alignment and magnetic anisotropy of a lanthanide-based metal-organic architecture by metal exchange, while preserving the network design.
Identifiants
pubmed: 35393751
doi: 10.1002/smll.202107073
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2107073Subventions
Organisme : BOREAS beamline
ID : 2020024200
Organisme : BOREAS beamline
ID : 2020094657
Organisme : Marie Sklodowska-Curie Actions
ID : 894924
Organisme : European Union's Horizon 2020
Organisme : IMDEA Nanociencia
Organisme : "Severo Ochoa" Programme for Centres of Excellence in R&D
ID : SEV-2016-0686
Organisme : European Research Council
ID : 766555
Pays : International
Informations de copyright
© 2022 The Authors. Small published by Wiley-VCH GmbH.
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