Real-time imaging of enzymatic degradation of pretreated maize internodes reveals different cell types have different profiles.

FTIR microspectroscopy Fluorescence Hot water pretreatment Lignocellulose Microspectrometry

Journal

Bioresource technology
ISSN: 1873-2976
Titre abrégé: Bioresour Technol
Pays: England
ID NLM: 9889523

Informations de publication

Date de publication:
Jun 2022
Historique:
received: 25 02 2022
revised: 05 04 2022
accepted: 06 04 2022
pubmed: 12 4 2022
medline: 27 4 2022
entrez: 11 4 2022
Statut: ppublish

Résumé

This work presents a dynamic view of the enzymatic degradation of maize cell walls, and sheds new light on the recalcitrance of hot water pretreated maize stem internodes. Infra-red microspectrometry, mass spectrometry, fluorescence recovery after photobleaching and fluorescence imaging were combined to investigate enzymatic hydrolysis at the cell scale. Depending on their polymer composition and organisation, cell types exhibits different extent and rate of enzymatic degradation. Enzymes act sequentially from the cell walls rich in accessible cellulose to the most recalcitrant cells. This phenomenon can be linked to the heterogeneous distribution of enzymes in the liquid medium and the adsorption/desorption mechanisms that differ with the type of cell.

Identifiants

pubmed: 35405211
pii: S0960-8524(22)00469-2
doi: 10.1016/j.biortech.2022.127140
pii:
doi:

Substances chimiques

Water 059QF0KO0R
Cellulose 9004-34-6
Lignin 9005-53-2

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

127140

Informations de copyright

Copyright © 2022 Elsevier Ltd. All rights reserved.

Auteurs

Amandine Leroy (A)

INRAE, UR 1268 BIA, 44316 Nantes, France; Université de Reims Champagne Ardenne, INRAE, FARE, UMR A614, 51100 Reims, France.

Marie-Françoise Devaux (MF)

INRAE, UR 1268 BIA, 44316 Nantes, France.

Mathieu Fanuel (M)

INRAE, UR 1268 BIA, 44316 Nantes, France; INRAE, BIBS Facility, 44316 Nantes, France.

Hugo Chauvet (H)

DISCO Beamline, SOLEIL Synchrotron, BP48, l'Orme des Merisiers, 91192 Gif-sur-Yvette CEDEX, France.

Sylvie Durand (S)

INRAE, UR 1268 BIA, 44316 Nantes, France.

Camille Alvarado (C)

INRAE, UR 1268 BIA, 44316 Nantes, France.

Anouck Habrant (A)

Université de Reims Champagne Ardenne, INRAE, FARE, UMR A614, 51100 Reims, France.

Christophe Sandt (C)

SMIS Beamline, SOLEIL Synchrotron, BP48, l'Orme des Merisiers, 91192 Gif-sur-Yvette CEDEX, France.

Hélène Rogniaux (H)

INRAE, UR 1268 BIA, 44316 Nantes, France; INRAE, BIBS Facility, 44316 Nantes, France.

Gabriel Paës (G)

Université de Reims Champagne Ardenne, INRAE, FARE, UMR A614, 51100 Reims, France.

Fabienne Guillon (F)

INRAE, UR 1268 BIA, 44316 Nantes, France. Electronic address: fabienne.guillon@inrae.fr.

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Classifications MeSH