Discovery of a Dysprosium Metallocene Single-Molecule Magnet with Two High-Temperature Orbach Processes.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
25 Apr 2022
Historique:
pubmed: 15 4 2022
medline: 15 4 2022
entrez: 14 4 2022
Statut: ppublish

Résumé

Magnetic bistability in single-molecule magnets (SMMs) is a potential basis for new types of nanoscale information storage material. The standard model for thermally activated relaxation of the magnetization in SMMs is based on the occurrence of a single Orbach process. Here, we show that incorporating a phosphorus atom into the framework of the dysprosium metallocene [(Cp

Identifiants

pubmed: 35420419
doi: 10.1021/acs.inorgchem.1c03980
pmc: PMC9044448
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6017-6025

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Auteurs

Fu-Sheng Guo (FS)

Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QR, U.K.

Mian He (M)

Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QR, U.K.

Guo-Zhang Huang (GZ)

Key Laboratory of Bioinorganic and Synthetic Chemistry of the Ministry of Education, School of Chemistry, Sun-Yat Sen University, Guangzhou 510006, P. R. China.

Sean R Giblin (SR)

School of Physics and Astronomy, Cardiff University, Cardiff CF24 3AA, U.K.

David Billington (D)

School of Physics and Astronomy, Cardiff University, Cardiff CF24 3AA, U.K.

Frank W Heinemann (FW)

Department of Chemistry and Pharmacy, Inorganic Chemistry, Friedrich-Alexander-University Erlangen-Nürnberg, Egerlandstrabe 1, 91058 Erlangen, Germany.

Ming-Liang Tong (ML)

Key Laboratory of Bioinorganic and Synthetic Chemistry of the Ministry of Education, School of Chemistry, Sun-Yat Sen University, Guangzhou 510006, P. R. China.

Akseli Mansikkamäki (A)

NMR Research Group, University of Oulu, P.O. Box 8000, Oulu FI-90014, Finland.

Richard A Layfield (RA)

Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QR, U.K.

Classifications MeSH