Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt.
Journal
RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657
Informations de publication
Date de publication:
14 Jan 2021
14 Jan 2021
Historique:
received:
22
12
2020
accepted:
11
01
2021
entrez:
15
4
2022
pubmed:
18
1
2021
medline:
18
1
2021
Statut:
epublish
Résumé
The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.
Identifiants
pubmed: 35424301
doi: 10.1039/d0ra10739e
pii: d0ra10739e
pmc: PMC8693991
doi:
Types de publication
Journal Article
Langues
eng
Pagination
3539-3546Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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