Pu(iii) and Cm(iii) in the presence of EDTA: aqueous speciation, redox behavior, and the impact of Ca(ii).
Journal
RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657
Informations de publication
Date de publication:
21 Mar 2022
21 Mar 2022
Historique:
received:
13
12
2021
accepted:
14
03
2022
entrez:
15
4
2022
pubmed:
16
4
2022
medline:
16
4
2022
Statut:
epublish
Résumé
The impact of calcium on the solubility, redox behavior, and speciation of the An(iii)-EDTA (An = Pu or Cm) system under reducing, anoxic conditions was investigated through batch solubility experiments, X-ray absorption spectroscopy (XAS), density functional theory (DFT), and time-resolved laser fluorescence spectroscopy (TRLFS). Batch solubility experiments were conducted from undersaturation using Pu(OH)
Identifiants
pubmed: 35424870
doi: 10.1039/d1ra09010k
pii: d1ra09010k
pmc: PMC8985188
doi:
Types de publication
Journal Article
Langues
eng
Pagination
9478-9493Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts of interest to declare.
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