Beyond the Threshold: A Study of Chalcogenophene-Based Two-Photon Initiators.
Journal
Chemistry of materials : a publication of the American Chemical Society
ISSN: 0897-4756
Titre abrégé: Chem Mater
Pays: United States
ID NLM: 9884133
Informations de publication
Date de publication:
12 Apr 2022
12 Apr 2022
Historique:
received:
22
11
2021
revised:
07
03
2022
entrez:
18
4
2022
pubmed:
19
4
2022
medline:
19
4
2022
Statut:
ppublish
Résumé
A series of nine soluble, symmetric chalcogenophenes bearing hexyl-substituted triphenylamines, indolocarbazoles, or phenylcarbazoles was designed and synthesized as potential two-photon absorption (2PA) initiators. A detailed photophysical analysis of these molecules revealed good 2PA properties of the series and, in particular, a strong influence of selenium on the 2PA cross sections, rendering these materials especially promising new 2PA photoinitiators. Structuring and threshold tests proved the efficiency and broad spectral versatility of two selenium-containing lead compounds as well as their applicability in an acrylate resin formulation. A comparison with commercial photoinitiators
Identifiants
pubmed: 35431440
doi: 10.1021/acs.chemmater.1c04002
pmc: PMC9009090
doi:
Types de publication
Journal Article
Langues
eng
Pagination
3042-3052Informations de copyright
© 2022 The Authors. Published by American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
Références
Adv Healthc Mater. 2020 Aug;9(15):e1900752
pubmed: 31347290
Opt Express. 2016 Apr 18;24(8):9053-66
pubmed: 27137334
J Chem Phys. 2006 Nov 14;125(18):184508
pubmed: 17115766
Lab Chip. 2016 May 24;16(11):1993-2013
pubmed: 27146365
Angew Chem Int Ed Engl. 2009;48(18):3244-66
pubmed: 19370705
Appl Opt. 2007 Apr 1;46(10):1819-29
pubmed: 17356626
J Phys Chem B. 2015 Jul 23;119(29):9254-67
pubmed: 25390209
Angew Chem Int Ed Engl. 2016 Mar 14;55(12):3862-81
pubmed: 26854878
Org Lett. 2011 Aug 5;13(15):4068-71
pubmed: 21732597
Nat Commun. 2019 Sep 25;10(1):4340
pubmed: 31554803
ACS Nano. 2012 Mar 27;6(3):2302-11
pubmed: 22324511
Adv Healthc Mater. 2020 Jan;9(1):e1901217
pubmed: 31746140
Nat Biotechnol. 2003 Nov;21(11):1369-77
pubmed: 14595365
Small. 2017 Sep;13(34):
pubmed: 28696538
Chem Rev. 2017 Aug 9;117(15):10212-10290
pubmed: 28756658
Angew Chem Int Ed Engl. 2018 Nov 12;57(46):15122-15127
pubmed: 30191643
Chem Rev. 2014 Jan 8;114(1):557-89
pubmed: 24083614
Adv Mater. 2021 Sep;33(37):e2101992
pubmed: 34337801
Photochem Photobiol Sci. 2010 Jul 30;9(7):908-15
pubmed: 20405075
Nature. 2016 Dec 14;540(7633):371-378
pubmed: 27974748
Opt Express. 2008 Mar 17;16(6):4029-47
pubmed: 18542501
Opt Express. 2019 May 27;27(11):15205-15221
pubmed: 31163720
Opt Lett. 1997 Jan 15;22(2):132-4
pubmed: 18183126
Photochem Photobiol. 2002 Apr;75(4):327-34
pubmed: 12003120
Analyst. 2019 May 7;144(9):3056-3063
pubmed: 30916075
J Am Chem Soc. 2001 Jul 4;123(26):6447-8
pubmed: 11427084
J Phys Chem Lett. 2017 Dec 7;8(23):5878-5883
pubmed: 29144140
Chemphyschem. 2017 Mar 3;18(5):549-563
pubmed: 27959475
Opt Lett. 2017 Feb 15;42(4):743-746
pubmed: 28198854
Opt Express. 2006 Jan 23;14(2):810-6
pubmed: 19503401
Adv Mater. 2014 Oct;26(38):6566-71
pubmed: 25146724
Phys Chem Chem Phys. 2014 Mar 14;16(10):4510-21
pubmed: 24244946
Proc Natl Acad Sci U S A. 2015 Sep 15;112(37):11502-7
pubmed: 26330605
Phys Chem Chem Phys. 2016 Jun 28;18(24):16404-13
pubmed: 27264847
Small. 2019 Oct;15(40):e1902687
pubmed: 31402578
Addit Manuf. 2019 Dec;30:
pubmed: 32864346
Angew Chem Int Ed Engl. 2007;46(33):6238-58
pubmed: 17654468
Sci Rep. 2020 May 26;10(1):8740
pubmed: 32457310
J Phys Chem A. 2009 Jul 23;113(29):8202-12
pubmed: 19569678
Opt Express. 2007 Oct 29;15(22):14488-97
pubmed: 19550727
Adv Healthc Mater. 2016 May;5(10):1233-43
pubmed: 27059425
Macromol Rapid Commun. 2019 Apr;40(8):e1900041
pubmed: 30861245
Rev Sci Instrum. 2013 Jul;84(7):073107
pubmed: 23902044
Science. 2019 Oct 4;366(6461):105-109
pubmed: 31604310
Angew Chem Int Ed Engl. 2017 Dec 11;56(50):15828-15845
pubmed: 28580704
Nat Commun. 2019 May 16;10(1):2179
pubmed: 31097713