Measurements and Utilization of Consistent Gibbs Energies of Transfer of Single Ions: Towards a Unified Redox Potential Scale for All Solvents.

electrochemistry ionic liquids salt bridges single ion Gibbs transfer energy thermodynamics

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
15 Jul 2022
Historique:
received: 16 02 2022
pubmed: 22 4 2022
medline: 19 7 2022
entrez: 21 4 2022
Statut: ppublish

Résumé

Utilizing the "ideal" ionic liquid salt bridge to measure Gibbs energies of transfer of silver ions between the solvents water, acetonitrile, propylene carbonate and dimethylformamide results in a consistent data set with a precision of 0.6 kJ mol

Identifiants

pubmed: 35446995
doi: 10.1002/chem.202200509
pmc: PMC9401597
doi:

Substances chimiques

Ions 0
Solvents 0
Water 059QF0KO0R
Silver 3M4G523W1G

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202200509

Subventions

Organisme : European Metrology Programme for Innovation and Research
ID : 17FUN09
Organisme : Deutsche Forschungsgemeinschaft
ID : KR2046/36-1
Organisme : Estonian Research Council
ID : PRG690

Informations de copyright

© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

Références

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Auteurs

Valentin Radtke (V)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Niklas Gebel (N)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Denis Priester (D)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Andreas Ermantraut (A)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Monika Bäuerle (M)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Daniel Himmel (D)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Regina Stroh (R)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Thorsten Koslowski (T)

Institut für Physikalische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 23a, 79104, Freiburg, Germany.

Ivo Leito (I)

Institute of Chemistry, University of Tartu, Ravila 14a Str, 50411, Tartu, Estonia.

Ingo Krossing (I)

Institut für Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF) and, Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

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Classifications MeSH