Core-Sheath-Like Poly(Ethylene Oxide)/Beeswax Composite Fibers Prepared by Single-Spinneret Electrospinning. Antibacterial, Antifungal, and Antitumor Activities.


Journal

Macromolecular bioscience
ISSN: 1616-5195
Titre abrégé: Macromol Biosci
Pays: Germany
ID NLM: 101135941

Informations de publication

Date de publication:
06 2022
Historique:
revised: 24 03 2022
received: 13 01 2022
pubmed: 23 4 2022
medline: 15 6 2022
entrez: 22 4 2022
Statut: ppublish

Résumé

Composite fibrous materials are prepared from poly(ethylene oxide) (PEO) and beeswax (BW) by single-spinneret electrospinning using chloroform as a common solvent. The obtained fibers have core-sheath-like structure, as evidenced by the water contact angle values and corroborated by the results on the elemental composition of the fiber's surface determined by X-ray photoelectron spectroscopy (XPS) and by analyses with scanning electron microscopy of fibers before and after selective extraction of PEO or BW. Furthermore, the core-sheath-like structure is proven by transmission electron microscopy. This is attributed to self-assembly of BW molecules on the surface of the formed fibers driven by the incompatibility between PEO and BW. 5-Nitro-8-hydroxyquinoline (NQ) is embedded as a model drug with antibacterial, antifungal, and anticancer properties in the PEO/BW fibrous materials. XPS analyses reveal that NQ is present on the surface of the PEO/BW/NQ materials. Using a purposely designed cell for fixation of the fibrous materials the NQ release in phosphate buffer solution with рН 7.4 is followed. The new PEO/BW/NQ fibrous materials exhibit antibacterial activity against S. aureus and E. coli, antifungal effect against C. albicans, and selective anticancer activity against HeLa (human cervical adenocarcinoma cells) and SH-4 (human melanoma cells) cell lines.

Identifiants

pubmed: 35451564
doi: 10.1002/mabi.202200015
doi:

Substances chimiques

Anti-Bacterial Agents 0
Antifungal Agents 0
Waxes 0
beeswax 2ZA36H0S2V
Polyethylene Glycols 3WJQ0SDW1A
Ethylene Oxide JJH7GNN18P

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2200015

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Selin Kyuchyuk (S)

Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Akad. G. Bonchev St., bl. 103A, Sofia, BG-1113, Bulgaria.

Dilyana Paneva (D)

Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Akad. G. Bonchev St., bl. 103A, Sofia, BG-1113, Bulgaria.

Daniela Karashanova (D)

Institute of Optical Materials and Technologies, Bulgarian Academy of Sciences, Akad. G. Bonchev St., bl. 109, Sofia, BG-1113, Bulgaria.

Nadya Markova (N)

Institute of Microbiology, Bulgarian Academy of Sciences, Akad. G. Bonchev St, bl. 26, Sofia, BG-1113, Bulgaria.

Ani Georgieva (A)

Institute of Experimental Morphology, Pathology and Anthropology with Museum, Bulgarian Academy of Sciences, Akad. G. Bonchev St, bl. 25, Sofia, BG-1113, Bulgaria.

Reneta Toshkova (R)

Institute of Experimental Morphology, Pathology and Anthropology with Museum, Bulgarian Academy of Sciences, Akad. G. Bonchev St, bl. 25, Sofia, BG-1113, Bulgaria.

Nevena Manolova (N)

Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Akad. G. Bonchev St., bl. 103A, Sofia, BG-1113, Bulgaria.

Iliya Rashkov (I)

Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Akad. G. Bonchev St., bl. 103A, Sofia, BG-1113, Bulgaria.

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