Selective organomercury determination by ICP-MS made easy.

Fish tissues ICP-MS Mercury speciation Methylmercury On-line separation Trace element

Journal

Analytica chimica acta
ISSN: 1873-4324
Titre abrégé: Anal Chim Acta
Pays: Netherlands
ID NLM: 0370534

Informations de publication

Date de publication:
08 May 2022
Historique:
received: 23 11 2021
revised: 19 01 2022
accepted: 23 01 2022
entrez: 27 4 2022
pubmed: 28 4 2022
medline: 29 4 2022
Statut: ppublish

Résumé

A fast and cost-effective procedure based on Inductively Coupled Plasma - Mass Spectrometry (ICP-MS) for the selective determination of methylmercury (MeHg) is proposed and validated for fish tissue analysis. Selectivity for MeHg is achieved by simply inserting a strong anion exchange resin to block inorganic mercury as negatively charged chloride species, leaving MeHg unretained. The procedure features a 15 min extraction time followed by a 100 s analysis time achieving a limit of detection of 1.6 μg kg

Identifiants

pubmed: 35473882
pii: S0003-2670(22)00124-6
doi: 10.1016/j.aca.2022.339553
pii:
doi:

Substances chimiques

Methylmercury Compounds 0
Mercury FXS1BY2PGL

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

339553

Informations de copyright

Copyright © 2022 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Davide Spanu (D)

Department of Science and High Technology, University of Insubria, Via Valleggio 11, Como, Italy. Electronic address: davide.spanu@uninsubria.it.

Laura Butti (L)

Department of Science and High Technology, University of Insubria, Via Valleggio 11, Como, Italy.

Ginevra Boldrocchi (G)

Department of Human Sciences, Innovation and Territory, University of Insubria, Via Valleggio 11, Como, Italy.

Roberta Bettinetti (R)

Department of Human Sciences, Innovation and Territory, University of Insubria, Via Valleggio 11, Como, Italy.

Sandro Recchia (S)

Department of Science and High Technology, University of Insubria, Via Valleggio 11, Como, Italy. Electronic address: sandro.recchia@uninsubria.it.

Damiano Monticelli (D)

Department of Science and High Technology, University of Insubria, Via Valleggio 11, Como, Italy. Electronic address: damiano.monticelli@uninsubria.it.

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Classifications MeSH