Unimolecular Nanoparticles toward More Precise Regulations of Self-Assembled Superlattices in Soft Matter.

Precise Control Self-Assembly Superlattices Unimolecular Nanoparticles

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
11 Jul 2022
Historique:
received: 05 03 2022
pubmed: 29 4 2022
medline: 29 4 2022
entrez: 28 4 2022
Statut: ppublish

Résumé

The hierarchical self-assembly process opens up great potential for the construction of nanostructural superlattices. Precise regulation of self-assembled superlattices, however, remains a challenge. Even when the primary molecules are precise, the supramolecular motifs (or secondary building blocks) can vary dramatically. In the present work, we propose the concept of unimolecular nanoparticles (UMNPs). The UMNPs act as the supramolecular motif and directly pack into the superlattices. A highly branched giant molecule is presented. We systematically explore its conformations and the superlattice of this giant molecule. Moreover, intriguing complex phases are discovered when blending this UMNP with other conventional giant molecules. These binary mixtures provide direct evidence to support our previously proposed self-sorting process in the self-assembly of "soft alloys". The concept of UMNPs offers a unique approach toward more precise regulation of self-assembled superlattices in soft matter.

Identifiants

pubmed: 35478477
doi: 10.1002/anie.202203433
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202203433

Subventions

Organisme : National Natural Science Foundation of China
ID : 51890870
Organisme : National Natural Science Foundation of China
ID : 51890871
Organisme : National Natural Science Foundation of China
ID : U1832220
Organisme : Project of Guangdong Province
ID : No. 2016ZT06C322
Organisme : Key-Area Research and Development Program of Guangdong Province
ID : No. 2019B121203003
Organisme : Key-Area Research and Development Program of Guangdong Province
ID : 2020B010182002

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Huanyu Lei (H)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.

Yuchu Liu (Y)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Tong Liu (T)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Qing-Yun Guo (QY)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Xiao-Yun Yan (XY)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Yicong Wang (Y)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.

Wei Zhang (W)

Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Zebin Su (Z)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Jiahao Huang (J)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

Wei Xu (W)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.

Feng-Gang Bian (FG)

Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201210, China.

Mingjun Huang (M)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China University of Technology, Guangzhou, 510640, China.

Stephen Z D Cheng (SZD)

South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou, 510640, China.
Department of Polymer Science, School of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA.

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