A Cu(ii)-MOF based on a propargyl carbamate-functionalized isophthalate ligand.


Journal

RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657

Informations de publication

Date de publication:
03 Jun 2021
Historique:
received: 06 04 2021
accepted: 01 06 2021
entrez: 28 4 2022
pubmed: 29 4 2022
medline: 29 4 2022
Statut: epublish

Résumé

A copper-based metal-organic framework (MOF) was prepared using a new linker, a 5-substituted isophthalic acid bearing a propargyl carbamate group, intended to provide a terminal alkyne function protruding from the material surface to generate supported gold species for potential catalytic applications. The novel material was fully characterized by spectroscopic analyses of different kinds: FTIR, Raman, EDX, and XPS, as well as by thermal and surface area measurements. Synchrotron X-ray diffraction data analysis, in particular, revealed that this MOF, labelled [Cu(1,3-YBDC)]·

Identifiants

pubmed: 35479884
doi: 10.1039/d1ra02686k
pii: d1ra02686k
pmc: PMC9034020
doi:

Types de publication

Journal Article

Langues

eng

Pagination

20429-20438

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Maria Cristina Cassani (MC)

Dept. of Industrial Chemistry "Toso Montanari", Bologna University Viale Risorgimento 4 I-40136 Bologna Italy maria.cassani@unibo.it daniele.nanni@unibo.it +39 051 2093700 +39 051 2093623.

Francesca Gambassi (F)

Dept. of Industrial Chemistry "Toso Montanari", Bologna University Viale Risorgimento 4 I-40136 Bologna Italy maria.cassani@unibo.it daniele.nanni@unibo.it +39 051 2093700 +39 051 2093623.

Barbara Ballarin (B)

Dept. of Industrial Chemistry "Toso Montanari", Bologna University Viale Risorgimento 4 I-40136 Bologna Italy maria.cassani@unibo.it daniele.nanni@unibo.it +39 051 2093700 +39 051 2093623.

Daniele Nanni (D)

Dept. of Industrial Chemistry "Toso Montanari", Bologna University Viale Risorgimento 4 I-40136 Bologna Italy maria.cassani@unibo.it daniele.nanni@unibo.it +39 051 2093700 +39 051 2093623.

Ilaria Ragazzini (I)

Dept. of Industrial Chemistry "Toso Montanari", Bologna University Viale Risorgimento 4 I-40136 Bologna Italy maria.cassani@unibo.it daniele.nanni@unibo.it +39 051 2093700 +39 051 2093623.

Davide Barreca (D)

CNR-ICMATE, INSTM, Dept. of Chemical Sciences, Padova University Via Marzolo 1 I-35131 Padova Italy.

Chiara Maccato (C)

Dept. of Chemical Sciences, Padova University, INSTM Via Marzolo 1 I-35131 Padova Italy.

Antonietta Guagliardi (A)

Institute of Crystallography, To.Sca.Lab, National Research Council via Valleggio 11 I-22100 Como Italy.

Norberto Masciocchi (N)

Dept. of Science and High Technology, To.Sca.Lab., University of Insubria via Valleggio 11 I-22100 Como Italy.

Alessandro Kovtun (A)

Institute of Organic Synthesis and Photoreactivity, (CNR-ISOF) Via P. Gobetti 101 I-40129 Bologna Italy.

Katia Rubini (K)

Dept. of Chemistry "Giacomo Ciamician", Bologna University Via Selmi 2 I-40126 Bologna Italy.

Elisa Boanini (E)

Dept. of Chemistry "Giacomo Ciamician", Bologna University Via Selmi 2 I-40126 Bologna Italy.

Classifications MeSH