Potentiometric detection of creatinine in the presence of nicotine: Molecular recognition, sensing and quantification through multivariate regression.
Journal
Talanta
ISSN: 1873-3573
Titre abrégé: Talanta
Pays: Netherlands
ID NLM: 2984816R
Informations de publication
Date de publication:
15 Aug 2022
15 Aug 2022
Historique:
received:
07
03
2022
revised:
07
04
2022
accepted:
08
04
2022
pubmed:
29
4
2022
medline:
10
6
2022
entrez:
28
4
2022
Statut:
ppublish
Résumé
Systematic errors in the calix [4] pyrrole-based potentiometric detection of creatinine have been observed in heavy smokers. This work further characterizes the interactions between the nicotinium cation and the cavitand as well as the resulting interference produced during the potentiometric detection. It is found that the nicotinium cation binds the electronic rich aromatic cavity defined by the pyrrole rings of the receptor's cone conformation with an estimated binding constant higher than 10
Identifiants
pubmed: 35483318
pii: S0039-9140(22)00269-7
doi: 10.1016/j.talanta.2022.123473
pii:
doi:
Substances chimiques
Cations
0
Pyrroles
0
Nicotine
6M3C89ZY6R
Creatinine
AYI8EX34EU
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
123473Informations de copyright
Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.