Iodine/water-mediated deprotective oxidation of allylic ethers to access α,β-unsaturated ketones and aldehydes.
Journal
RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657
Informations de publication
Date de publication:
08 Apr 2020
08 Apr 2020
Historique:
received:
25
02
2020
accepted:
03
04
2020
entrez:
2
5
2022
pubmed:
14
4
2020
medline:
14
4
2020
Statut:
epublish
Résumé
The first iodine/water-mediated deprotective oxidation of allylic ethers to access α,β-unsaturated ketones and aldehydes was achieved. The reaction tolerates a wide range of functionalities. Furthermore, this protocol was found to be applicable to the oxidative transformation of allylic acetates. The proposed mechanism involves an oxygen transfer from solvent water to the carbonyl products.
Identifiants
pubmed: 35497130
doi: 10.1039/d0ra02625e
pii: d0ra02625e
pmc: PMC9052112
doi:
Types de publication
Journal Article
Langues
eng
Pagination
14720-14724Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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