Synthesis through 3D printing: formation of 3D coordination polymers.


Journal

RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657

Informations de publication

Date de publication:
08 Apr 2020
Historique:
received: 28 02 2020
accepted: 03 04 2020
entrez: 2 5 2022
pubmed: 16 4 2020
medline: 16 4 2020
Statut: epublish

Résumé

Coordination polymers (CPs) and coordination network solids such as metal-organic frameworks (MOFs) have gained increasing interest during recent years due to their unique properties and potential applications. Preparing 3D printed structures using CP would provide many advantages towards utilization in fields such as catalysis and sensing. So far, functional 3D structures were printed mostly by dispersing pre-synthesized particles of CPs and MOFs within a polymerizable carrier. This resulted in a CP active material dispersed within a 3D polymeric object, which may obstruct or impede the intrinsic properties of the CP. Here, we present a new concept for obtaining 3D free-standing objects solely composed of CP material, starting from coordination metal complexes as the monomeric building blocks, and utilizing the 3D printer itself as a tool to

Identifiants

pubmed: 35497148
doi: 10.1039/d0ra01887b
pii: d0ra01887b
pmc: PMC9052092
doi:

Types de publication

Journal Article

Langues

eng

Pagination

14812-14817

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Oded Halevi (O)

Casali Center for Applied Chemistry, Institute of Chemistry, The Hebrew University of Jerusalem Jerusalem 91904 Israel magdassi@mail.huji.ac.il.
School of Materials Science and Engineering, Nanyang Technological University 639798 Singapore pslee@ntu.edu.sg.
Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE) 138602 Singapore.

Jingwei Chen (J)

School of Materials Science and Engineering, Nanyang Technological University 639798 Singapore pslee@ntu.edu.sg.
Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE) 138602 Singapore.

Gurunathan Thangavel (G)

School of Materials Science and Engineering, Nanyang Technological University 639798 Singapore pslee@ntu.edu.sg.

Samuel Alexander Morris (SA)

School of Materials Science and Engineering, Nanyang Technological University 639798 Singapore pslee@ntu.edu.sg.

Tal Ben Uliel (T)

Department of Chemistry, Bar-Ilan University Ramat-Gan 5290002 Israel.

Yaakov Raphael Tischler (YR)

Department of Chemistry, Bar-Ilan University Ramat-Gan 5290002 Israel.

Pooi See Lee (PS)

School of Materials Science and Engineering, Nanyang Technological University 639798 Singapore pslee@ntu.edu.sg.
Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE) 138602 Singapore.

Shlomo Magdassi (S)

Casali Center for Applied Chemistry, Institute of Chemistry, The Hebrew University of Jerusalem Jerusalem 91904 Israel magdassi@mail.huji.ac.il.
Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE) 138602 Singapore.

Classifications MeSH