A photoredox catalysed Heck reaction
Journal
RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657
Informations de publication
Date de publication:
23 Nov 2020
23 Nov 2020
Historique:
received:
14
10
2020
accepted:
19
11
2020
entrez:
6
5
2022
pubmed:
25
11
2020
medline:
25
11
2020
Statut:
epublish
Résumé
The attachment of homoleptic Ru bis-terpy complexes on graphene oxide significantly improved the photocatalytic activity of the complexes. These straightforward complexes were applied as photocatalysts in a Heck reaction. Due to covalent functionalization on graphene oxide, which functions as an electron reservoir, excellent yields were obtained. DFT investigations of the charge redistribution revealed efficient hole transfer from the excited Ru unit towards the graphene oxide.
Identifiants
pubmed: 35514879
doi: 10.1039/d0ra08749a
pii: d0ra08749a
pmc: PMC9058128
doi:
Types de publication
Journal Article
Langues
eng
Pagination
42930-42937Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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