A multi-technique study of altered granitic rock from the Krunkelbach Valley uranium deposit, Southern Germany.


Journal

RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657

Informations de publication

Date de publication:
03 Jul 2020
Historique:
received: 15 04 2020
accepted: 11 06 2020
entrez: 6 5 2022
pubmed: 6 7 2020
medline: 6 7 2020
Statut: epublish

Résumé

Herein, a multi-technique study was performed to reveal the elemental speciation and microphase composition in altered granitic rock collected from the Krunkelbach Valley uranium (U) deposit area near an abandoned U mine, Black Forest, Southern Germany. The former Krunkelbach U mine with 1-2 km surrounding area represents a unique natural analogue site with the rich accumulation of secondary U minerals suitable for radionuclide migration studies from a spent nuclear fuel (SNF) repository. Based on a micro-technique analysis using several synchrotron-based techniques such as X-ray fluorescence analysis, X-ray absorption spectroscopy, powder X-ray diffraction and laboratory-based scanning electron microscopy and Raman spectroscopy, the complex mineral assemblage was identified. While on the surface of granite, heavily altered metazeunerite-metatorbernite (Cu(UO

Identifiants

pubmed: 35518608
doi: 10.1039/d0ra03375h
pii: d0ra03375h
pmc: PMC9055283
doi:

Types de publication

Journal Article

Langues

eng

Pagination

25529-25539

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

Authors declare no conflict of interests.

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Auteurs

Ivan Pidchenko (I)

The Rossendorf Beamline at ESRF - The European Synchrotron CS40220 38043 Grenoble Cedex 9 France kristina.kvashnina@esrf.fr ivan.pidchenko@gmail.com.
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology PO Box 510119 01314 Dresden Germany.

Stephen Bauters (S)

The Rossendorf Beamline at ESRF - The European Synchrotron CS40220 38043 Grenoble Cedex 9 France kristina.kvashnina@esrf.fr ivan.pidchenko@gmail.com.
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology PO Box 510119 01314 Dresden Germany.

Irina Sinenko (I)

Lomonosov Moscow State University, Department of Chemistry 119991 Moscow Russia.

Simone Hempel (S)

Technical University Dresden, Institute of Construction Materials DE-01062 Dresden Germany.

Lucia Amidani (L)

The Rossendorf Beamline at ESRF - The European Synchrotron CS40220 38043 Grenoble Cedex 9 France kristina.kvashnina@esrf.fr ivan.pidchenko@gmail.com.
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology PO Box 510119 01314 Dresden Germany.

Dirk Detollenaere (D)

Department of Chemistry, X-ray Imaging and Microspectroscopy Research Group, Ghent University Ghent Belgium.
Dutch-Belgian Beamline (DUBBLE), European Synchrotron Radiation Facility 71 Avenue des Martyrs, CS 40220 38043 Grenoble Cedex 9 France.

Laszlo Vinze (L)

Department of Chemistry, X-ray Imaging and Microspectroscopy Research Group, Ghent University Ghent Belgium.

Dipanjan Banerjee (D)

Department of Chemistry, KU Leuven Celestijnenlaan 200F, Box 2404 B-3001 Leuven Belgium.
Dutch-Belgian Beamline (DUBBLE), European Synchrotron Radiation Facility 71 Avenue des Martyrs, CS 40220 38043 Grenoble Cedex 9 France.

Roelof van Silfhout (R)

The University of Manchester, School of Electrical and Electronic Engineering Sackville Street Manchester M13 9PL UK.

Stepan N Kalmykov (SN)

Lomonosov Moscow State University, Department of Chemistry 119991 Moscow Russia.

Jörg Göttlicher (J)

Karlsruhe Institute of Technology, Institute for Photon Science and Synchrotron Radiation (IPS) P.O. 3640 D-76021 Karlsruhe Germany.

Robert J Baker (RJ)

School of Chemistry, University of Dublin, Trinity College Dublin 2 Ireland.

Kristina O Kvashnina (KO)

The Rossendorf Beamline at ESRF - The European Synchrotron CS40220 38043 Grenoble Cedex 9 France kristina.kvashnina@esrf.fr ivan.pidchenko@gmail.com.
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology PO Box 510119 01314 Dresden Germany.
Lomonosov Moscow State University, Department of Chemistry 119991 Moscow Russia.

Classifications MeSH