Gas-phase degradation of 2-butanethiol initiated by OH radicals and Cl atoms: kinetics, product yields and mechanism at 298 K and atmospheric pressure.


Journal

RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657

Informations de publication

Date de publication:
17 Jul 2019
Historique:
received: 29 05 2019
accepted: 14 07 2019
entrez: 6 5 2022
pubmed: 22 7 2019
medline: 22 7 2019
Statut: epublish

Résumé

Relative rate coefficients and product distribution of the reaction of 2-butanethiol (2butSH) with OH radicals and Cl atoms were obtained at atmospheric pressure and 298 K. The experiments were performed in a 480 L borosilicate glass photoreactor in synthetic air coupled to a long path "

Identifiants

pubmed: 35519461
doi: 10.1039/c9ra04051j
pii: c9ra04051j
pmc: PMC9067059
doi:

Types de publication

Journal Article

Langues

eng

Pagination

22618-22626

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Alejandro L Cardona (AL)

LUQCA-Instituto de Investigaciones en Fisicoquímica de Córdoba, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba Ciudad Universitaria 5000 Córdoba Argentina mteruel@fcq.unc.edu.ar.

Rodrigo G Gibilisco (RG)

Institute for Atmospheric and Environmental Research, Bergische Universität Wuppertal 42097 Wuppertal Germany.

María B Blanco (MB)

LUQCA-Instituto de Investigaciones en Fisicoquímica de Córdoba, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba Ciudad Universitaria 5000 Córdoba Argentina mteruel@fcq.unc.edu.ar.

Peter Wiesen (P)

Institute for Atmospheric and Environmental Research, Bergische Universität Wuppertal 42097 Wuppertal Germany.

Mariano Teruel (M)

LUQCA-Instituto de Investigaciones en Fisicoquímica de Córdoba, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba Ciudad Universitaria 5000 Córdoba Argentina mteruel@fcq.unc.edu.ar.

Classifications MeSH