Asymmetric Radical Cyclization of Alkenes by Stereospecific Homolytic Substitution of Sulfinamides.
Asymmetric Synthesis
Cyclization
Homolytic Substitution
Radical Reactions
Sulfinamide
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
18 07 2022
18 07 2022
Historique:
received:
21
01
2022
pubmed:
14
5
2022
medline:
14
7
2022
entrez:
13
5
2022
Statut:
ppublish
Résumé
We report a novel asymmetric radical cyclization of alkenes via stereospecific homolytic substitution of sulfinamides. This reaction produces a variety of cyclic sulfinamides with excellent stereocontrol. The protocol features broad functional group tolerance, high product diversity, and easy accessibility to feedstocks, and outlines a new pathway for the synthesis of chiral cyclic sulfinamides.
Identifiants
pubmed: 35561057
doi: 10.1002/anie.202201027
doi:
Substances chimiques
Alkenes
0
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201027Informations de copyright
© 2022 Wiley-VCH GmbH.
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