Molecular Transport within Polymer Brushes: A FRET View at Aqueous Interfaces.
FRET
molecular transport
polymer brushes
spatially-resolved
wettability
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
09 May 2022
09 May 2022
Historique:
received:
20
04
2022
revised:
04
05
2022
accepted:
05
05
2022
entrez:
14
5
2022
pubmed:
15
5
2022
medline:
20
5
2022
Statut:
epublish
Résumé
Molecular permeability through polymer brush chains is implicated in surface lubrication, wettability, and solute capture and release. Probing molecular transport through polymer brushes can reveal information on the polymer nanostructure, with a permeability that is dependent on chain conformation and grafting density. Herein, we introduce a brush system to study the molecular transport of fluorophores from an aqueous droplet into the external "dry" polymer brush with the vapour phase above. The brushes consist of a random copolymer of
Identifiants
pubmed: 35566393
pii: molecules27093043
doi: 10.3390/molecules27093043
pmc: PMC9102696
pii:
doi:
Substances chimiques
Polymers
0
Solutions
0
Water
059QF0KO0R
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : 496201730 (BE 7737/2-1)
Organisme : Deutsche Forschungsgemeinschaft
ID : 422852551-SPP2171
Organisme : Deutsche Forschungsgemeinschaft
ID : 265191195-SFB1194
Références
ACS Appl Mater Interfaces. 2013 Feb;5(4):1400-7
pubmed: 23360664
J Phys Chem B. 2018 Aug 30;122(34):8309-8314
pubmed: 30132324
Nano Lett. 2006 Mar;6(3):573-8
pubmed: 16522065
Angew Chem Int Ed Engl. 2021 Sep 1;60(36):19988-19996
pubmed: 34337845
J Am Chem Soc. 2009 Feb 18;131(6):2070-1
pubmed: 19159287
Langmuir. 2019 Oct 22;35(42):13646-13655
pubmed: 31558025
ACS Nano. 2020 Aug 25;14(8):9938-9952
pubmed: 32667780
Langmuir. 2021 Mar 16;37(10):3049-3056
pubmed: 33667098
Langmuir. 2017 Aug 1;33(30):7468-7478
pubmed: 28737039
Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7468-71
pubmed: 23761266
Angew Chem Int Ed Engl. 2021 Jul 19;60(30):16600-16606
pubmed: 33979032
Soft Matter. 2019 Jan 30;15(5):937-946
pubmed: 30644495
Soft Matter. 2015 Nov 21;11(43):8508-16
pubmed: 26371862
Adv Colloid Interface Sci. 2021 Aug;294:102442
pubmed: 34118473
Soft Matter. 2020 May 7;16(17):4274-4282
pubmed: 32307507
Biomater Sci. 2021 Nov 9;9(22):7379-7391
pubmed: 34693954
ACS Appl Mater Interfaces. 2020 Dec 9;12(49):55243-55254
pubmed: 33233878
Langmuir. 2012 May 8;28(18):7212-22
pubmed: 22500465
Anal Chem. 2015 Dec 1;87(23):11746-54
pubmed: 26558486
Biophys J. 2011 Nov 16;101(10):2417-25
pubmed: 22098740
J Fluoresc. 2008 Nov;18(6):1093-101
pubmed: 18431548
Langmuir. 2020 Sep 8;36(35):10351-10360
pubmed: 32852216
J Mater Chem B. 2014 Nov 21;2(43):7544-7550
pubmed: 32261891
ACS Nano. 2022 Feb 22;16(2):3383-3393
pubmed: 35112848
Chem Rec. 2010 Aug;10(4):208-16
pubmed: 20533448
ACS Appl Polym Mater. 2022 May 13;4(5):3062-3087
pubmed: 35601464
ACS Nano. 2008 Jan;2(1):41-52
pubmed: 19206546
Nanoscale. 2019 Nov 14;11(42):19636-19657
pubmed: 31603455