Effect of Spatial Inhomogeneity on Quantum Trapping.


Journal

The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034

Informations de publication

Date de publication:
26 May 2022
Historique:
pubmed: 17 5 2022
medline: 17 5 2022
entrez: 16 5 2022
Statut: ppublish

Résumé

An object that is immersed in a fluid and approaching a substrate may find a potential energy minimum at a certain distance due to the balance between attractive and repulsive Casimir-Lifshitz forces, a phenomenon referred to as quantum trapping. This equilibrium depends on the relative values of the dielectric functions of the materials involved. Herein, we study quantum trapping effects in planar nanocomposite materials and demonstrate that they are strongly dependent on the characteristics of the spatial inhomogeneity. As a model case, we consider spherical particles embedded in an otherwise homogeneous material. We propose an effective medium approximation that accounts for the effect of inclusions and find that an unprecedented and counterintuitive intense repulsive Casimir-Lifshitz force arises as a result of the strong optical scattering and absorption size-dependent resonances caused by their presence. Our results imply that the proper analysis of quantum trapping effects requires comprehensive knowledge and a detailed description of the potential inhomogeneity (caused by imperfections, pores, inclusions, and density variations) present in the materials involved.

Identifiants

pubmed: 35576163
doi: 10.1021/acs.jpclett.2c00807
pmc: PMC9150094
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

4513-4519

Références

Nature. 1969 Dec 20;224(5225):1197-8
pubmed: 5360550
J Mater Chem A Mater. 2016 Feb 7;4(5):1953-1961
pubmed: 27019714
Phys Rev Lett. 2008 Oct 17;101(16):163603
pubmed: 18999669
Nature. 2021 Sep;597(7875):214-219
pubmed: 34497392
Biophys J. 1970 Jul;10(7):646-63
pubmed: 5449915
J Phys Chem C Nanomater Interfaces. 2015 Mar 12;119(10):5663-5670
pubmed: 26405466
J Opt Soc Am A Opt Image Sci Vis. 2001 Jun;18(6):1275-8
pubmed: 11393620
Science. 2019 Jun 07;364(6444):984-987
pubmed: 31171696
Appl Opt. 2007 Nov 20;46(33):8118-33
pubmed: 18026551
J Opt Soc Am A Opt Image Sci Vis. 2016 Jul 1;33(7):1244-56
pubmed: 27409680
J Phys Chem Lett. 2019 Oct 3;10(19):5856-5860
pubmed: 31424947
Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Nov;88(5):052133
pubmed: 24329240
Appl Opt. 2001 Mar 20;40(9):1354-61
pubmed: 18357121

Auteurs

Victoria Esteso (V)

Institute of Materials Science of Seville, Consejo Superior de Investigaciones Científicas (CSIC), Universidad de Sevilla (US), Américo Vespucio 49, 41092 Seville, Spain.

Sol Carretero-Palacios (S)

Departamento de Física de Materiales, Instituto de Materiales Nicolás Cabrera, Universidad Autónoma de Madrid, 28049 Madrid, Spain.

Hernán Míguez (H)

Institute of Materials Science of Seville, Consejo Superior de Investigaciones Científicas (CSIC), Universidad de Sevilla (US), Américo Vespucio 49, 41092 Seville, Spain.

Classifications MeSH