Advances towards Cell-Specific Gene Transfection: A Small-Molecule Approach Allows Order-of-Magnitude Selectivity.

biotin cancer cell targeting cell-penetrating peptides gene technology small molecules

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
01 Aug 2022
Historique:
received: 30 12 2021
pubmed: 24 5 2022
medline: 5 8 2022
entrez: 23 5 2022
Statut: ppublish

Résumé

A transfection vector that can home in on tumors is reported. Whereas previous vectors that allow moderately cell selective gene transfection used larger systems, this small-molecule approach paved the way for precise structure-activity relationship optimization. For this, biotin, which mediates cell selectivity, was combined with the potent DNA-binding motif tetralysine-guanidinocarbonypyrrol via a hydrophilic linker, thus enabling SAR-based optimization. The new vector mediated biotin receptor (BR)-selective transfection of cell lines with different BR expression levels. Computer-based analyses of microscopy images revealed a preference of one order of magnitude for the BR-positive cell lines over the BR-negative controls.

Identifiants

pubmed: 35604769
doi: 10.1002/chem.202104618
pmc: PMC9401007
doi:

Substances chimiques

Biotin 6SO6U10H04

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202104618

Subventions

Organisme : Deutsche Forschungsgemeinschaft
Organisme : Evonik Stiftung

Informations de copyright

© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Thies Dirksmeyer (T)

Institute of Organic Chemistry, University of Duisburg-Essen, 45117, Essen, Germany.

Paul Stahl (P)

Institute of Biology, University of Duisburg-Essen, 45117, Essen, Germany.

Cecilia Vallet (C)

Institute of Biology, University of Duisburg-Essen, 45117, Essen, Germany.

Shirley Knauer (S)

Institute of Biology, University of Duisburg-Essen, 45117, Essen, Germany.

Michael Giese (M)

Institute of Organic Chemistry, University of Duisburg-Essen, 45117, Essen, Germany.

Carsten Schmuck (C)

Institute of Organic Chemistry, University of Duisburg-Essen, 45117, Essen, Germany.

Christoph Hirschhäuser (C)

Institute of Organic Chemistry, University of Duisburg-Essen, 45117, Essen, Germany.

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Classifications MeSH