New Mechanism for Long Photo-Induced Enhanced Raman Spectroscopy in Au Nanoparticles Embedded in TiO
TiO
2
cathodoluminescence
nanoparticles
photo-induced charge separation
photo-induced enhanced Raman spectroscopy
surface enhanced Raman spectroscopy
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Jun 2022
Jun 2022
Historique:
revised:
27
04
2022
received:
18
02
2022
pubmed:
27
5
2022
medline:
27
5
2022
entrez:
26
5
2022
Statut:
ppublish
Résumé
The photo-induced enhanced Raman spectroscopy (PIERS) effect is a phenomenon taking place when plasmonic nanoparticles deposited on a semiconductor are illuminated by UV light prior to Raman measurement. Results from the literature show that the PIERS effect lasts for about an hour. The proposed mechanism for this effect is the creation of oxygen vacancies in the semiconductor that would create a path for charge transfer between the analyte and the nanoparticles. However, this hypothesis has never been confirmed experimentally. Furthermore, the tested structure of the PIERS substrate has always been composed of plasmonic nanoparticles deposited on top of the semiconductor. Here, gold nanoparticles co-deposited with porous TiO
Identifiants
pubmed: 35616163
doi: 10.1002/smll.202201088
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2201088Informations de copyright
© 2022 Wiley-VCH GmbH.
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