Turning Electronic Waste to Continuous-Flow Reactor Using Porous Aromatic Frameworks.

Extraction of valuable metals such as gold from electronic wastes (e-waste) is regarded as a promising way of environmental remediation; however, this process is still confronted with the cost-ineffective product for normal usages like electronic devices or jewelry. Therefore, there would be merits in directly converting gold from e-waste to materials of higher value, for example, catalysts for pollutant treatment. Herein, a porous aromatic framework (PAF) with cationic sites, named iPAF-7, was synthesized and exhibited rapid extraction of gold from e-waste. Au@iPAF-7 completely converted nitroarenes to arylamines within 10 s at a rate constant of 7.8 × 10