Chiral control of spin-crossover dynamics in Fe(II) complexes.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
Jul 2022
Jul 2022
Historique:
received:
13
08
2021
accepted:
14
03
2022
pubmed:
27
5
2022
medline:
27
5
2022
entrez:
26
5
2022
Statut:
ppublish
Résumé
Iron-based spin-crossover complexes hold tremendous promise as multifunctional switches in molecular devices. However, real-world technological applications require the excited high-spin state to be kinetically stable-a feature that has been achieved only at cryogenic temperatures. Here we demonstrate high-spin-state trapping by controlling the chiral configuration of the prototypical iron(II)tris(4,4'-dimethyl-2,2'-bipyridine) in solution, associated for stereocontrol with the enantiopure Δ- or Λ-enantiomer of tris(3,4,5,6-tetrachlorobenzene-1,2-diolato-κ
Identifiants
pubmed: 35618767
doi: 10.1038/s41557-022-00933-0
pii: 10.1038/s41557-022-00933-0
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
739-745Subventions
Organisme : Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation)
ID : NCCR MUST
Informations de copyright
© 2022. The Author(s), under exclusive licence to Springer Nature Limited.
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