Development of photoluminescent artificial nacre-like nanocomposite from polyester resin and graphene oxide.
lanthanide-doped strontium aluminate
photoluminescence
smart artificial nacre
superhydrophobic
unsaturated polyester
Journal
Microscopy research and technique
ISSN: 1097-0029
Titre abrégé: Microsc Res Tech
Pays: United States
ID NLM: 9203012
Informations de publication
Date de publication:
Sep 2022
Sep 2022
Historique:
revised:
12
05
2022
received:
07
04
2022
accepted:
15
05
2022
pubmed:
28
5
2022
medline:
24
8
2022
entrez:
27
5
2022
Statut:
ppublish
Résumé
Long-lasting phosphorescent nacre-like material was simply prepared from a nanocomposite of inorganic and organic materials. Low molecular weight unsaturated polyester (PET), graphene oxide (GO), and nanoparticles of rare-earth activated aluminate pigment were used in the preparation process of an organic/inorganic hybrid nanocomposite. Using methylethylketone peroxide (MEKP) as a hardener, we were able to develop a fluid solution that hardens within minutes at room temperature. Covalent and hydrogen bonds were introduced between the polyester resin and graphene oxide nanosheets. The interface interactions of those bonds resulted in toughness, excellent tensile strength, and high durability. The produced nacre substrates demonstrated long-persistent and reversible luminescence. The excitation of the produced nacre substrates at 365 nm resulted in a 524 nm emission. After being exposed to UV light, the photoluminescent nacre substrates became green. The increased superhydrophobic activity of the produced nacre substrates was achieved without affecting their physico-mechanical properties. HIGHLIGHTS: Colorless photoluminescent smart nacre-like nanocomposites were prepared. Graphene oxide and polyester were mixed with phosphor nanoparticles at 25°C. Photostable long-persistent phosphorescence lighting was observed in the dark. Photochromic change to green emission was detected under ultraviolet light. The nacre-like composites exhibit improved hardness and hydrophobicity.
Substances chimiques
Dental Materials
0
Nacre
0
Polyesters
0
graphene oxide
0
Graphite
7782-42-5
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3104-3114Subventions
Organisme : Princes Nourah bint Abdelrhman
ID : PNURSP2022R22
Informations de copyright
© 2022 Wiley Periodicals LLC.
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