A High-Valent Ru-PCP Pincer Catalyst for Hydrogenation of Carbonyl and Carboxyl Compounds under Molecular Hydrogen.
cooperative catalysis
esters
high-valent ruthenium
hydrogenation
pincer complexes
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
06 Jul 2022
06 Jul 2022
Historique:
received:
10
04
2022
pubmed:
1
6
2022
medline:
1
6
2022
entrez:
31
5
2022
Statut:
ppublish
Résumé
Low-valent metals traditionally dominate the domain of catalytic hydrogenation. However, metal-ligand cooperating (MLC) catalytic systems, operating through heterolytic H-H bond splitting by a Lewis acidic metal and a basic ligand site, do not require an electron-rich metal. On the contrary, high-valent metals that induce weaker back donation facilitate heterolytic bond activation. Here we report, for the first time, the efficient hydrogenation of carbonyl and carboxyl compounds under molecular hydrogen catalyzed by a structurally well-defined Ru
Identifiants
pubmed: 35638170
doi: 10.1002/chem.202201098
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201098Subventions
Organisme : German-Israeli Foundation for Scientific Research and Development
ID : I-1508-302.5/2019
Organisme : Israel Science Foundation
ID : 370/20
Organisme : State Key Laboratory of Bio-organic and Natural Products Chemistry
Organisme : the Neubauer Family Foundation
Informations de copyright
© 2022 Wiley-VCH GmbH.
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