Modulation of Slow Magnetic Relaxation in Gd(III)-Tetrahalosemiquinonate Complexes.
electron paramagnetic resonance
exchange interactions
lanthanides
magnetic properties
relaxation
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
15 Jul 2022
15 Jul 2022
Historique:
revised:
26
05
2022
received:
31
03
2022
pubmed:
2
6
2022
medline:
2
6
2022
entrez:
1
6
2022
Statut:
ppublish
Résumé
Incorporating lanthanoid(III)-radical magnetic exchange coupling is a possible route to improving the performance of lanthanoid (Ln) single-molecule magnets (SMMs), molecular materials that exhibit slow relaxation and low temperature quantum tunnelling of the magnetization. Complexes of Gd(III) can conveniently be used as model systems to study the Ln-radical exchange coupling, thanks to the absence of the orbital angular momentum that is present for many Ln(III) ions. Two new Gd(III)-radical compounds of formula [Gd(18-c-6)X
Identifiants
pubmed: 35644855
doi: 10.1002/asia.202200325
pmc: PMC9400849
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202200325Subventions
Organisme : AINSE Limited (AINSE Post-Graduate Research Award)
Organisme : Australian Government for a Research Training Program
Organisme : Australian Research Council
ID : DP170100034 and LE210100009
Organisme : Australian Centre for Neutron Scattering
Organisme : Australian Nuclear Science and Technology Organisation
Organisme : Australian Government through the National Collaborative Research Infrastructure Strategy
Informations de copyright
© 2022 The Authors. Chemistry - An Asian Journal published by Wiley-VCH GmbH.
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