Trimetallic Iridium-Nickel-Iridium Bis(formazanate) Assemblies.

Formazans have attracted a lot of attention in coordination chemistry since the early 1940s because of their unique properties engendered by the nitrogen-rich conjugated backbone. Although many studies have been done using formazanates to chelate transition metals, research using formazanates as building blocks for polynuclear compounds and supramolecular chemistry remains rare. In this paper, we describe a synthetic strategy that uses a pyridyl-substituted bis(formazanato)nickel complex as a metalloligand to further assemble with two [Ir(C^N)