Surface-Induced Dissociation for Protein Complex Characterization.

High-resolution mass spectrometry Native mass spectrometry Protein complex Protein mass spectrometry Proteoform identification Surface-induced dissociation

Journal

Methods in molecular biology (Clifton, N.J.)
ISSN: 1940-6029
Titre abrégé: Methods Mol Biol
Pays: United States
ID NLM: 9214969

Informations de publication

Date de publication:
2022
Historique:
entrez: 3 6 2022
pubmed: 4 6 2022
medline: 9 6 2022
Statut: ppublish

Résumé

Native mass spectrometry (nMS) enables intact non-covalent complexes to be studied in the gas phase. nMS can provide information on composition, stoichiometry, topology, and, when coupled with surface-induced dissociation (SID), subunit connectivity. Here we describe the characterization of protein complexes by nMS and SID. Substructural information obtained using this method is consistent with the solved complex structure, when a structure exists. This provides confidence that the method can also be used to obtain substructural information for unknowns, providing insight into subunit connectivity and arrangements. High-energy SID can also provide information on proteoforms present. Previously SID has been limited to a few in-house modified instruments and here we focus on SID implemented within an in-house-modified Q Exactive UHMR. However, SID is currently commercially available within the Waters Select Series Cyclic IMS instrument. Projects are underway that involve the NIH-funded native MS resource (nativems.osu.edu), instrument vendors, and third-party vendors, with the hope of bringing the technology to more platforms and labs in the near future. Currently, nMS resource staff can perform SID experiments for interested research groups.

Identifiants

pubmed: 35657596
doi: 10.1007/978-1-0716-2325-1_15
doi:

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

211-237

Subventions

Organisme : NIGMS NIH HHS
ID : P41 GM128577
Pays : United States

Informations de copyright

© 2022. The Author(s), under exclusive license to Springer Science+Business Media, LLC, part of Springer Nature.

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Auteurs

Sophie R Harvey (SR)

Department of Chemistry and Biochemistry and Resource for Native Mass Spectrometry Guided Structural Biology, The Ohio State University, Columbus, OH, USA.

Gili Ben-Nissan (G)

Department of Biomolecular Sciences, Weizmann Institute of Science, Rehovot, Israel.

Michal Sharon (M)

Department of Biomolecular Sciences, Weizmann Institute of Science, Rehovot, Israel.

Vicki H Wysocki (VH)

Department of Chemistry and Biochemistry and Resource for Native Mass Spectrometry Guided Structural Biology, The Ohio State University, Columbus, OH, USA. wysocki.11@osu.edu.

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