Elution with 1,2-Hexanediol Enables Coupling of ICPMS with Reversed-Pase Liquid Chromatography under Standard Conditions.
Journal
Analytical chemistry
ISSN: 1520-6882
Titre abrégé: Anal Chem
Pays: United States
ID NLM: 0370536
Informations de publication
Date de publication:
21 06 2022
21 06 2022
Historique:
pubmed:
7
6
2022
medline:
23
6
2022
entrez:
6
6
2022
Statut:
ppublish
Résumé
The inductively coupled plasma mass spectrometry (ICPMS) has been attracting increasing attention for many applications as an element-selective chromatographic detector. A major and fundamental limitation in coupling ICPMS with liquid chromatography is the limited compatibility with organic solvents, which has so far been addressed via a tedious approach, collectively referred to as the "organic ICPMS mode", that can decrease detection sensitivity by up to 100-fold. Herein, we report 1,2-hexanediol as a new eluent in high-performance liquid chromatography-ICPMS which enables avoiding the current limitations. Unlike commonly used eluents, 1,2-hexanediol was remarkably compatible with ICPMS detection at high flow rates of 1.5 mL min
Identifiants
pubmed: 35666989
doi: 10.1021/acs.analchem.2c01769
pmc: PMC9218959
doi:
Substances chimiques
Glycols
0
Hexanes
0
Indicators and Reagents
0
Arsenic
N712M78A8G
1,2-hexanediol
TR046Y3K1G
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
8802-8810Références
Sci Total Environ. 2019 Feb 15;651(Pt 2):1839-1848
pubmed: 30317172
Anal Chem. 2013 Oct 1;85(19):9321-7
pubmed: 23984920
J Chromatogr A. 2002 Jul 26;964(1-2):91-8
pubmed: 12198859
Anal Chem. 2021 Apr 27;93(16):6335-6341
pubmed: 33847492
Anal Chim Acta. 2015 Jul 23;885:33-56
pubmed: 26231891
Anal Chim Acta. 2019 Apr 11;1053:22-31
pubmed: 30712566
Chemosphere. 2013 Nov;93(9):2187-94
pubmed: 24016626
J Environ Sci (China). 2016 Nov;49:97-103
pubmed: 28007184
J Chem Inf Model. 2007 Nov-Dec;47(6):2140-8
pubmed: 17985865
Chemosphere. 2020 Jan;239:124781
pubmed: 31514006
Anal Chim Acta. 2020 Jan 15;1094:11-17
pubmed: 31761036
Anal Chim Acta. 2017 Jun 29;974:43-53
pubmed: 28535880
Metallomics. 2016 Aug 1;8(8):774-81
pubmed: 27276690
Anal Chim Acta. 2015 Jul 23;885:57-91
pubmed: 26231892
Anal Chem. 2012 Jul 17;84(14):5851-7
pubmed: 22725632
Angew Chem Weinheim Bergstr Ger. 2016 Apr 18;128(17):5345-5348
pubmed: 27478276
Anal Chem. 2014 Oct 21;86(20):10282-7
pubmed: 25241916
Cutan Ocul Toxicol. 2009;28(1):23-4
pubmed: 19514921
Chemosphere. 2021 Oct;281:130819
pubmed: 33991903
Food Chem Toxicol. 2018 Aug;118:245-251
pubmed: 29752981
Anal Chim Acta. 2019 Nov 4;1079:20-29
pubmed: 31387711
Electrophoresis. 1999 Jan;20(1):100-10
pubmed: 10065965
Mass Spectrom Rev. 2022 Jan;41(1):32-50
pubmed: 32997814
Anal Chim Acta. 2019 Sep 27;1073:1-21
pubmed: 31146831
Ecotoxicology. 2017 Jan;26(1):81-89
pubmed: 27866342
Metallomics. 2021 Aug 12;13(8):
pubmed: 34302346
Metallomics. 2017 Oct 18;9(10):1429-1438
pubmed: 28932845
J Chromatogr A. 2014 Apr 25;1339:50-8
pubmed: 24657146
J Agric Food Chem. 2012 Mar 7;60(9):2083-9
pubmed: 22339408
Anal Bioanal Chem. 2018 Jan;410(3):661-667
pubmed: 28735451
Talanta. 2014 Apr;121:89-96
pubmed: 24607114
Anal Chim Acta. 2015 Sep 24;894:7-19
pubmed: 26423624
Ecotoxicol Environ Saf. 2020 Sep 15;201:110796
pubmed: 32505050