Dendrite-Free and Long-Cycling Lithium Metal Battery Enabled by Ultrathin, 2D Shield-Defensive, and Single Lithium-Ion Conducting Polymeric Membrane.
2D molecular brushes
layer-by-layer stacking
lithium metal batteries
polymeric membranes
shield defense
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Aug 2022
Aug 2022
Historique:
revised:
19
05
2022
received:
20
10
2021
pubmed:
10
6
2022
medline:
10
6
2022
entrez:
9
6
2022
Statut:
ppublish
Résumé
Polymeric membranes are considered as promising materials to realize safe and long-life lithium metal batteries (LMBs). However, they are usually based on soft 1D linear polymers and thus cannot effectively inhibit piercing of lithium dendrites at high current density. Herein, single lithium-ion conducting molecular brushes (GO-g-PSSLi) are successfully designed and fabricated with a new 2D "soft-hard-soft" hierarchical structure by grafting hairy lithium polystyrenesulfonate (PSSLi) chains on both sides of graphene oxide (GO) sheets. The ultrathin GO-g-PSSLi membrane is further constructed by evaporation-induced layer-by-layer self-assembly of GO-g-PSSLi molecular brushes. Unlike conventional soft 1D linear polymeric structure, the rigid 2D extended aromatic structure of intralayer GO backbones can bear the shield effect of preventing the dendrites possibly generated at high current density from piercing. More importantly, such a shield effect can be significantly strengthened by layer-by-layer stacking of 2D molecular brushes. On the other hand, the 3D interconnected interlayer channels and the soft single lithium-ion conducting PSSLi side-chains on the surface of channels provide rapid lithium-ion transportation pathways and homogenize lithium-ion flux. As a result, LMBs with GO-g-PSSLi membrane possess long-term reversible lithium plating/striping (6 months) at high current density.
Identifiants
pubmed: 35680119
doi: 10.1002/adma.202108437
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2108437Subventions
Organisme : National Natural Science Foundation of China
ID : 51925308
Organisme : National Natural Science Foundation of China
ID : 51872336
Organisme : National Key Research and Development Program of China
ID : 2021YFF0500600
Organisme : Technical and Innovation Talents of Guangdong Special Support Program
ID : 2017TX04C248
Organisme : Science and Technology Program of Guangzhou
ID : 202002020041
Informations de copyright
© 2022 Wiley-VCH GmbH.
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