2,2,3,3,3-Pentafluoro-1-propanol and its dimer: structural diversity, conformational conversion, and tunnelling motion.


Journal

Physical chemistry chemical physics : PCCP
ISSN: 1463-9084
Titre abrégé: Phys Chem Chem Phys
Pays: England
ID NLM: 100888160

Informations de publication

Date de publication:
22 Jun 2022
Historique:
pubmed: 11 6 2022
medline: 11 6 2022
entrez: 10 6 2022
Statut: epublish

Résumé

Rotational spectra of 2,2,3,3,3-pentafluoro-1-propanol (PFP) were measured using cavity and chirped pulse Fourier transform microwave spectrometers. Of the nine possible PFP configurations which include four mirror-imaged pairs and an achiral conformer, the two most stable monomeric PFP imaged pairs,

Identifiants

pubmed: 35686993
doi: 10.1039/d2cp01895k
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14975-14984

Auteurs

Bowei Wu (B)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.

Nathan A Seifert (NA)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.
Chemistry and Chemical & Biomedical Engineering Department, University of New Haven, 300 Boston Post Rd, West Haven, CT, 06516, USA.

Aran Insausti (A)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.
Departamento de Química Física, Universidad del País Vasco (UPVEHU) Barrio Sarriena s/n, Leioa, Spain.
Instituto Biofisika (UPV/EHU, CSIC) Barrio Sarriena s/n, Leioa, Spain.

Jiarui Ma (J)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.

Sönke Oswald (S)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.
Institut für Physikalische Chemie, Georg-August-Universität Göttingen, 37077 Göttingen, Germany.

Wolfgang Jäger (W)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.

Yunjie Xu (Y)

Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada. yunjie.xu@ualberta.ca.

Classifications MeSH