Iron-Catalyzed Fluoromethylene Transfer from a Sulfonium Reagent.

Alkenes / chemistry Catalysis Indicators and Reagents Iron / chemistry Molecular Structure

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
24 06 2022
Historique:
pubmed: 15 6 2022
medline: 28 6 2022
entrez: 14 6 2022
Statut: ppublish

Résumé

Herein, we report the first example of an iron porphyrin catalyzed fluoromethylene transfer from (2,4-dimethylphenyl)(fluoromethyl)(phenyl)sulfonium tetrafluoroborate to unactivated alkenes. The fluorocarbene or fluoromethylene synthon is the smallest "organic"

Identifiants

DOI: 10.1021/acs.orglett.2c01757 PMID: 35699424
pubmed: 35699424
doi: 10.1021/acs.orglett.2c01757
doi:

Substances chimiques

Alkenes 0
Indicators and Reagents 0
Iron E1UOL152H7

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4474-4478

Auteurs

Arturs Sperga (A)

Latvian Institute of Organic Synthesis, Aizkraukles 21, LV-1006 Riga, Latvia.

Dzintars Zacs (D)

Institute of Food Safety, Animal Health and Environment "BIOR", Lejupes iela 3, Riga LV-1076, Latvia.

Janis Veliks (J)

Latvian Institute of Organic Synthesis, Aizkraukles 21, LV-1006 Riga, Latvia.
ORCID: 0000-0003-0955-8257

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures acycliques › Alcènes › Iron-Catalyzed Fluoromethylene Transfer from a...
questionsmedicales.fr › Phénomènes chimiques › Catalyse › Iron-Catalyzed Fluoromethylene Transfer from a...
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Produits chimiques de laboratoire › Indicateurs et réactifs › Iron-Catalyzed Fluoromethylene Transfer from a...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Fer › Iron-Catalyzed Fluoromethylene Transfer from a...
questionsmedicales.fr › Phénomènes chimiques › Structure moléculaire › Iron-Catalyzed Fluoromethylene Transfer from a...