Synthesis of a Triphenylphosphinimide-Substituted Silirane as a "Masked" Acyclic Silylene.

Phosphinimides are long known as useful ligands in transition metal chemistry, but examples of these in low-valent silicon chemistry are rather rare. Hence, in this work, we report on the implementation of a triphenylphosphinimide moiety as a ligand of a novel silylene that is trapped as a silirane with cyclohexene. By performing activation reactions with B(