Analysis of samples of high explosives extracted from explosive remnants of war.
Explosive remnants of war
Fourier transform infrared spectroscopy
Impact sensitivity
Thermal analysis
Unexploded ordnance
Journal
The Science of the total environment
ISSN: 1879-1026
Titre abrégé: Sci Total Environ
Pays: Netherlands
ID NLM: 0330500
Informations de publication
Date de publication:
10 Oct 2022
10 Oct 2022
Historique:
received:
04
04
2022
revised:
17
06
2022
accepted:
17
06
2022
pubmed:
26
6
2022
medline:
18
8
2022
entrez:
25
6
2022
Statut:
ppublish
Résumé
Millions of tonnes of dumped ammunition and explosive remnants of war remain in nature both on land and at sea. It is well known that the ordnance could represent a definite explosive risk if disturbed, and that some of the constituents in the ammunition could be harmful to humans and the environment. Nevertheless, a tacit assumption by decision makers is that, if left alone, the ammunition will slowly become harmless over time. Explosive remnants of war, however, represent not only an environmental risk but also a security and safety risk, as members of the public could come into contact with them, and fear is growing that ageing munitions could explode and/or be misused. In recent years, several concerns have been raised regarding the presence of dumped ammunition and explosive remnants of war, the potential dangers they represent, and the fact that the deterioration rate of the explosives could be significantly lower than previously assumed. In the present work, thermal and impact sensitivity studies of high explosives extracted from explosive remnants of war were performed, to determine whether or not the explosives have deteriorated to such a degree that a noteworthy decrease in performance and/or impact sensitivity can be recorded. The thermal behaviour of the explosives was studied using thermogravimetry analysis, and the impact sensitivity was determined using a fallhammer machine and the Bruceton test procedure. The thermal and impact sensitivity results obtained in the analysis indicated no deterioration of high explosives in the examined explosive remnants of war that would denote any significant reduction in performance and/or impact sensitivity.
Identifiants
pubmed: 35752239
pii: S0048-9697(22)03961-4
doi: 10.1016/j.scitotenv.2022.156864
pii:
doi:
Substances chimiques
Explosive Agents
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
156864Informations de copyright
Copyright © 2022. Published by Elsevier B.V.
Déclaration de conflit d'intérêts
Declaration of competing interest Geir P. Novik reports financial support was provided by Norwegian Defence Research Establishment.