Orbital analysis of bonding in diarylhalonium salts and relevance to periodic trends in structure and reactivity.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
07 Jun 2022
Historique:
received: 03 02 2022
accepted: 10 05 2022
entrez: 27 6 2022
pubmed: 28 6 2022
medline: 28 6 2022
Statut: epublish

Résumé

Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis. The three center, four electron (3c-4e) bond is a center piece of their reactivity, but structural variation among the diarylhaloniums, and in comparison with other λ

Identifiants

pubmed: 35756513
doi: 10.1039/d2sc02332f
pii: d2sc02332f
pmc: PMC9172531
doi:

Types de publication

Journal Article

Langues

eng

Pagination

6532-6540

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Shubhendu S Karandikar (SS)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

Avik Bhattacharjee (A)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

Bryan E Metze (BE)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

Nicole Javaly (N)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

Edward J Valente (EJ)

Department of Chemistry, University of Portland Portland OR 97203 USA.

Theresa M McCormick (TM)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

David R Stuart (DR)

Department of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.

Classifications MeSH