Supercapacitor based on polymeric binary composite of polythiophene and single-walled carbon nanotubes.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
04 Jul 2022
Historique:
received: 19 02 2022
accepted: 24 06 2022
entrez: 5 7 2022
pubmed: 6 7 2022
medline: 6 7 2022
Statut: epublish

Résumé

The aim of this work is to fabricate supercapacitor electrode based on poly (3-hexyl-thiophene-2, 5-diyl) (P3HT) and single-walled carbon nanotubes (SWCNTs) nanocomposites with different ratios onto a graphite sheet as a substrate with a wide voltage window in nonaqueous electrolyte. Structural, morphological and electrochemical properties of the prepared nanocomposites of P3HT/SWCNTs were studied and discussed. The electrochemical properties included cyclic voltammetry (CV), galvanostatic charging-discharging (GCD), and electrochemical impedance spectroscopy (EIS) were investigated. The obtained results indicated that P3HT/SWCNTs nanocomposite possesses higher specific capacitance than that present in its individual component. The high electrochemical performance of the nanocomposite was due to formation of microporous structure which facilitates ions diffusion and electrolyte penetration in these pores. The morphological micrographs of the purified SWCNTs had buckypaper structure while the photomicrographs of P3HT/SWCNTs showed that SWCNTs appear behind and front of the P3HT nanospheres. The specific capacitance of 50% SWCNTs at 0.5 Ag

Identifiants

pubmed: 35789198
doi: 10.1038/s41598-022-15477-z
pii: 10.1038/s41598-022-15477-z
pmc: PMC9253121
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

11278

Informations de copyright

© 2022. The Author(s).

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Auteurs

Azza Shokry (A)

Department of Materials Science, Institute of Graduate Studies and Research, Alexandria University, 163 Horrya Avenue, El-Shatby, P.O.Box 832, Alexandria, Egypt. azzashokry@alexu.edu.eg.

Marwa Karim (M)

Physics Department, Faculty of Science, Alexandria University, Moharram Bek, P.O. Box 21511, Alexandria, Egypt.

Marwa Khalil (M)

Department of Nanotechnology and Composite Materials, Institute of New Materials and Advanced Technology, City of Scientific Research and Technological Applications (SRTA-City), New Borg El Arab City, P.O. Box 21934, Alexandria, Egypt.

Shaker Ebrahim (S)

Department of Materials Science, Institute of Graduate Studies and Research, Alexandria University, 163 Horrya Avenue, El-Shatby, P.O.Box 832, Alexandria, Egypt.

Jehan El Nady (J)

Electronic Materials Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City, P.O. Box 21934, Alexandria, Egypt.

Classifications MeSH