Photocycloaddition as a Tool for Modulation of the Lower Critical Solution Temperature in a Molecular π-System to Control Transmission of Solar Radiation.
Lower Critical Solution Temperature (LCST)
Photocycloaddition
Small-Molecule π-System
Smart Windows
Solar Radiation Control
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
26 Aug 2022
26 Aug 2022
Historique:
received:
24
05
2022
pubmed:
9
7
2022
medline:
9
7
2022
entrez:
8
7
2022
Statut:
ppublish
Résumé
Diels-Alder photocycloaddition, a well-known textbook reaction, has not been explored in materials chemistry. Herein we describe how this classical photochemistry can be used to modulate the lower critical solution temperature (LCST) of a molecular π-system, which can further be exploited for the controlled transmission of solar radiation for the management of indoor heat and light. An amphiphilic anthracene derivative 9-PA-1 exhibited LCST behavior at 27-32 °C with a reversible transition from a transparent to an opaque phase in water (1-5 mM). Irradiation of a toluene solution of 9-PA-1 with 365 nm light resulted in a [4+2] photocycloadduct 9-PA-2, which exhibited a modulated LCST behavior at 25-27 °C, at a concentration as low as 6 μM. The photocycloaddition of 9-PA-1 was significantly retarded in water, making it a stable candidate for the design of sustainable smart windows. We also demonstrated 100 cm
Identifiants
pubmed: 35801523
doi: 10.1002/anie.202207641
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202207641Subventions
Organisme : Science and Engineering Research Board
ID : SB/S2/RJN-058/2016
Organisme : Science and Engineering Research Board
ID : SB/S2/JCB-11/2014
Informations de copyright
© 2022 Wiley-VCH GmbH.
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