Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes.
Homogeneous Catalysis
Iridium
Quantum Tunneling
Silanes
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
05 Sep 2022
05 Sep 2022
Historique:
received:
28
03
2022
pubmed:
15
7
2022
medline:
15
7
2022
entrez:
14
7
2022
Statut:
ppublish
Résumé
An unprecedented quantum tunneling effect has been observed in catalytic Si-H bond activations at room temperature. The cationic hydrido-silyl-iridium(III) complex, {Ir[SiMe(o-C
Identifiants
pubmed: 35833924
doi: 10.1002/anie.202204558
pmc: PMC9545861
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202204558Subventions
Organisme : Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España
ID : PID2019-111281GB-I00
Organisme : Eusko Jaurlaritza
ID : IT1880-19
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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