Photolytic insertion of carbon monoxide into nitrosyl chloride: formation of nitrosoformyl chloride.

Journal

Physical chemistry chemical physics : PCCP
ISSN: 1463-9084
Titre abrégé: Phys Chem Chem Phys
Pays: England
ID NLM: 100888160

Informations de publication

Date de publication:
27 Jul 2022
Historique:
pubmed: 16 7 2022
medline: 16 7 2022
entrez: 15 7 2022
Statut: epublish

Résumé

Nitrosocarbonyls are exotic intermediates that remain scarcely characterized. By UV photolysis (365 nm) of nitrosyl chloride (ClNO) embedded in solid CO ice at 20 K, the elusive nitrosoformyl chloride (ClC(O)NO) has been synthesized

Identifiants

DOI: 10.1039/d2cp02913h PMID: 35837884
pubmed: 35837884
doi: 10.1039/d2cp02913h
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

17673-17678

Auteurs

Bo Lu (B)

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, China. xqzeng@fudan.edu.cn.

Xin Jiang (X)

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, China. xqzeng@fudan.edu.cn.

Xiaoqing Zeng (X)

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, China. xqzeng@fudan.edu.cn.
ORCID: 0000-0003-4611-2094

Classifications MeSH