Monomeric Magnesium Catalyzed Alkene and Alkyne Hydroboration.
X-ray structure
carbazole
magnesium
monomeric complexes
phosphorous
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
07 Oct 2022
07 Oct 2022
Historique:
received:
20
06
2022
pubmed:
22
7
2022
medline:
22
7
2022
entrez:
21
7
2022
Statut:
ppublish
Résumé
In this work, two monomeric magnesium alkyl complexes (1 and 2) were prepared using bis(phosphino)carbazole framework and among them 1 has been used as a catalyst for hydroboration of alkenes and alkynes with pinacolborane (HBpin). A broad variety of aromatic and aliphatic alkenes and alkynes were efficiently reduced. Anti-Markovnikov regioselective hydroboration of alkenes and alkynes was achieved, which was confirmed by deuterium-labelling experiments. The work represents the first example of the use of magnesium in homogeneous catalytic hydroboration of alkene with broad substrate scope. Experimental mechanistic investigations and DFT calculations provided insights into the reaction mechanism. Finally, the hydroboration protocol was extended to terpenes.
Identifiants
pubmed: 35862652
doi: 10.1002/chem.202201896
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201896Subventions
Organisme : STARS
ID : MoE-STARS/STARS-1/255
Informations de copyright
© 2022 Wiley-VCH GmbH.
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